Regioselective solvation in a polymeric lithium amide: remarkable twisted ladder structure of [{[PhCH2N(H)Li]2•H2NCH2Ph}∞]

Alan R. Kennedy; Robert E. Mulvey; Alan Robertson

doi:10.1039/A706615E

Regioselective solvation in a polymeric lithium amide: remarkable twisted ladder structure of [{[PhCH₂N(H)Li]₂•H₂NCH₂Ph}∞]

Alan R. Kennedy, Robert E. Mulvey, Alan Robertson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The hemi-benzylamine complex of lithium benzylamide exists in the crystal as an infinite, twisted-ladder structure of fused (NLi)₂ rings; curiously, one edge of the ladder is solvated by benzylamine molecules, while the other is solvent-free.

Original language	English
Pages (from-to)	89-90
Number of pages	2
Journal	Chemical Communications
Volume	1998
Issue number	1
DOIs	https://doi.org/10.1039/A706615E
Publication status	Published - 7 Jan 1998

Keywords

crystal structures
polymeric lithium amide
MO

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10.1039/A706615E

Cite this

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title = "Regioselective solvation in a polymeric lithium amide: remarkable twisted ladder structure of [{[PhCH2N(H)Li]2•H2NCH2Ph}∞]",

abstract = "The hemi-benzylamine complex of lithium benzylamide exists in the crystal as an infinite, twisted-ladder structure of fused (NLi)2 rings; curiously, one edge of the ladder is solvated by benzylamine molecules, while the other is solvent-free.",

keywords = "crystal structures, polymeric lithium amide, MO",

author = "Kennedy, {Alan R.} and Mulvey, {Robert E.} and Alan Robertson",

year = "1998",

month = jan,

day = "7",

doi = "10.1039/A706615E",

language = "English",

volume = "1998",

pages = "89--90",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Regioselective solvation in a polymeric lithium amide

T2 - remarkable twisted ladder structure of [{[PhCH2N(H)Li]2•H2NCH2Ph}∞]

AU - Kennedy, Alan R.

AU - Mulvey, Robert E.

AU - Robertson, Alan

PY - 1998/1/7

Y1 - 1998/1/7

N2 - The hemi-benzylamine complex of lithium benzylamide exists in the crystal as an infinite, twisted-ladder structure of fused (NLi)2 rings; curiously, one edge of the ladder is solvated by benzylamine molecules, while the other is solvent-free.

AB - The hemi-benzylamine complex of lithium benzylamide exists in the crystal as an infinite, twisted-ladder structure of fused (NLi)2 rings; curiously, one edge of the ladder is solvated by benzylamine molecules, while the other is solvent-free.

KW - crystal structures

KW - polymeric lithium amide

KW - MO

UR - http://pubs.rsc.org/en/Content/ArticleLanding/1998/CC/a706615e#!divAbstract

U2 - 10.1039/A706615E

DO - 10.1039/A706615E

M3 - Article

SN - 1359-7345

VL - 1998

SP - 89

EP - 90

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Regioselective solvation in a polymeric lithium amide: remarkable twisted ladder structure of [{[PhCH₂N(H)Li]₂•H₂NCH₂Ph}∞]

Abstract

Keywords

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Regioselective solvation in a polymeric lithium amide: remarkable twisted ladder structure of [{[PhCH2N(H)Li]2•H2NCH2Ph}∞]

Abstract

Keywords

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Regioselective solvation in a polymeric lithium amide: remarkable twisted ladder structure of [{[PhCH₂N(H)Li]₂•H₂NCH₂Ph}∞]