Abstract
Olefins possessing tethered β-functionalised phosphonate functionality have been shown to be effective cyclisation partners within intermolecular Pauson-Khand processes. The optimised protocol described facilitates intermolecular cyclisations with high levels of olefinic regiocontrol.
| Original language | English |
|---|---|
| Pages (from-to) | 649-653 |
| Number of pages | 5 |
| Journal | Synlett |
| Volume | 2010 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 25 Jan 2010 |
Keywords
- alkyne complexes
- annulations
- β-functionalised phosphonates
- Pauson-Khand reaction
- regioselectivity
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