Regioselective Pauson-Khand processes with olefins possessing extended phosphonates

Jacek L. Kędzia, William J. Kerr, Allan R. McPherson

Research output: Contribution to journalArticle

3 Citations (Scopus)
12 Downloads (Pure)

Abstract

Olefins possessing tethered β-functionalised phosphonate functionality have been shown to be effective cyclisation partners within intermolecular Pauson-Khand processes. The optimised protocol described facilitates intermolecular cyclisations with high levels of olefinic regiocontrol.
Original languageEnglish
Pages (from-to)649-653
Number of pages5
JournalSynlett
Volume2010
Issue number4
DOIs
Publication statusPublished - 25 Jan 2010

Keywords

  • alkyne complexes
  • annulations
  • β-functionalised phosphonates
  • Pauson-Khand reaction
  • regioselectivity

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