Regioselective Pauson-Khand processes with olefins possessing extended phosphonates

Jacek L. Kędzia, William J. Kerr, Allan R. McPherson

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Olefins possessing tethered β-functionalised phosphonate functionality have been shown to be effective cyclisation partners within intermolecular Pauson-Khand processes. The optimised protocol described facilitates intermolecular cyclisations with high levels of olefinic regiocontrol.
LanguageEnglish
Pages649-653
Number of pages5
JournalSynlett
Volume2010
Issue number4
DOIs
Publication statusPublished - 25 Jan 2010

Fingerprint

Organophosphonates
Cyclization
Alkenes

Keywords

  • alkyne complexes
  • annulations
  • β-functionalised phosphonates
  • Pauson-Khand reaction
  • regioselectivity

Cite this

Kędzia, Jacek L. ; Kerr, William J. ; McPherson, Allan R. / Regioselective Pauson-Khand processes with olefins possessing extended phosphonates. In: Synlett. 2010 ; Vol. 2010, No. 4. pp. 649-653.
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Regioselective Pauson-Khand processes with olefins possessing extended phosphonates. / Kędzia, Jacek L.; Kerr, William J.; McPherson, Allan R.

In: Synlett, Vol. 2010, No. 4, 25.01.2010, p. 649-653.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Kędzia, Jacek L.

AU - Kerr, William J.

AU - McPherson, Allan R.

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AB - Olefins possessing tethered β-functionalised phosphonate functionality have been shown to be effective cyclisation partners within intermolecular Pauson-Khand processes. The optimised protocol described facilitates intermolecular cyclisations with high levels of olefinic regiocontrol.

KW - alkyne complexes

KW - annulations

KW - β-functionalised phosphonates

KW - Pauson-Khand reaction

KW - regioselectivity

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