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Using a specially designed magnesium metallating manifold, combining kinetically activated TMP amide base with a sterically amplified β-diketiminate ligand, this study has established a new regioselective strategy for magnesiation of challenging N-heterocyclic molecules. The broad scope of the approach is illustrated through reactions of pyrazine, triazoles and substituted pyridines through isolation and structural elucidation of their magnesiated intermediates.
- magnesium metallating manifold
- regioselective strategy
- N-heterocyclic molecules
- chrage density
- deprotonative metalation
FingerprintDive into the research topics of 'Regioselective magnesiation of N-heterocyclic molecules: securing insecure cyclic anions by a β-diketiminate-magnesium clamp'. Together they form a unique fingerprint.
- 1 Finished
MIXMETAPPS: Tailoring Mixed-Metal Chemistry For Frontier Synthetic And Catalytic Applications (ERC Starting Grant)
1/10/11 → 31/03/17