Projects per year
Abstract
We present a series of compounds by exploiting the unusual 1,4-aryl shift observed for electron-rich 1,3-dithiole-2-thione and tetrathiafulvalene (TTF) derivatives in the presence of perchloric acid. The mechanistic features of this rearrangement are discussed since this synthetic strategy provides an alternative route for the synthesis and functionalisation of sulfur rich compounds including redox active compounds of TTFs, and a Ni dithiolene.
Original language | English |
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Pages (from-to) | 1002-1014 |
Number of pages | 13 |
Journal | Beilstein Journal of Organic Chemistry |
Volume | 6 |
DOIs | |
Publication status | Published - 21 Oct 2010 |
Keywords
- aldehydes
- tetrathiafulvalene
- metal-coordination
- sulfur heterocycles
Fingerprint Dive into the research topics of 'Redox-active tetrathiafulvalene and dithiolene compounds derived from allylic 1,4-diol rearrangement products of disubstituted 1,3-dithiole derivatives'. Together they form a unique fingerprint.
Projects
- 2 Finished
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SELF ASSEMBLING CONJUGATED MACROMOLECULES FOR ORGANIC FIELD EFFECT TRANSISTORS AND SOLAR CELLS
Skabara, P.
EPSRC (Engineering and Physical Sciences Research Council)
1/04/07 → 31/05/10
Project: Research