Recent developments in oxidative processes in steroid chemistry

Jorge A. R. Salvador; Samuel M. Silvestre; Vania M. Moreira

doi:10.2174/138527212800564204

Recent developments in oxidative processes in steroid chemistry

Jorge A. R. Salvador, Samuel M. Silvestre, Vania M. Moreira

Strathclyde Institute Of Pharmacy And Biomedical Sciences

Research output: Contribution to journal › Review article

8 Citations (Scopus)

Abstract

Oxygenated steroids are bioactive compounds and valuable intermediates in the synthesis of biologically active products and APIs. This review will cover the literature from 2005/06 to the present concerning allylic oxidation, epoxidation and syn-dihydroxylation of alkenes, alcohol oxidation, and remote functionalization reactions of steroidal substrates.

Original language	English
Pages (from-to)	1243-1276
Number of pages	34
Journal	Current Organic Chemistry
Volume	16
Issue number	10
DOIs	https://doi.org/10.2174/138527212800564204
Publication status	Published - 15 May 2012

Keywords

alcohol oxidation
allylic oxidation
catalysis
epoxidation
remote functionalization
steroids

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abstract = "Oxygenated steroids are bioactive compounds and valuable intermediates in the synthesis of biologically active products and APIs. This review will cover the literature from 2005/06 to the present concerning allylic oxidation, epoxidation and syn-dihydroxylation of alkenes, alcohol oxidation, and remote functionalization reactions of steroidal substrates.",

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author = "Salvador, {Jorge A. R.} and Silvestre, {Samuel M.} and Moreira, {Vania M.}",

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AU - Salvador, Jorge A. R.

AU - Silvestre, Samuel M.

AU - Moreira, Vania M.

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N2 - Oxygenated steroids are bioactive compounds and valuable intermediates in the synthesis of biologically active products and APIs. This review will cover the literature from 2005/06 to the present concerning allylic oxidation, epoxidation and syn-dihydroxylation of alkenes, alcohol oxidation, and remote functionalization reactions of steroidal substrates.

AB - Oxygenated steroids are bioactive compounds and valuable intermediates in the synthesis of biologically active products and APIs. This review will cover the literature from 2005/06 to the present concerning allylic oxidation, epoxidation and syn-dihydroxylation of alkenes, alcohol oxidation, and remote functionalization reactions of steroidal substrates.

KW - alcohol oxidation

KW - allylic oxidation

KW - catalysis

KW - epoxidation

KW - remote functionalization

KW - steroids

UR - http://www.eurekaselect.com/97908

U2 - 10.2174/138527212800564204

DO - 10.2174/138527212800564204

M3 - Review article

VL - 16

SP - 1243

EP - 1276

JO - Current Organic Chemistry

JF - Current Organic Chemistry

SN - 1385-2728

IS - 10

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