Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles

L Cuesta, D C Gerbino, E Hevia, D Morales, M E N Clemente, J Perez, L Riera, V Riera, D Miguel, I del Rio, S Garcia-Granda

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Abstract

The hydroxo compounds [Re(OH)(CO)(3)(N-N)] (N-N = bipy, 2a; Me-2-bipy, 2b) were prepared in a biphasic H2O/CH2Cl2 medium by reaction of [Re(OTf)(CO)(3)(N-N)] with KOH. In contrast, when anhydrous CH2Cl2 was used, the binuclear hydroxo-bridged compound [{Re(CO)(3)-(bipy)}(2)(mu-OH)]OTf (3-OTf) was obtained. Compound [Re(OH)(CO)(3)-(Me-2-bipy)] (2b) reacted with phenyl acetate or vinyl acetate to afford [Re(OAc)(CO)(3)(Me-2-bipy)] (4) and phenol or acetaldehyde, respectively. The reactions of [Mo(OH)(eta(3)- C3H4-Me-2)(CO)(2)(phen)] (1), 2a, and 2b toward several unsaturated organic electrophiles were studied. The reaction of 1 with (p-tolyl)isocyanate afforded an adduct of N,N'-di(p-tolyl)-urea and the carbonato-bridged compound [(Mo(eta(3)-C3H4-Me-2)(CO)(2)-(phen)}(2)(mu-eta(1)(O),eta(1)(O)-CO3)] (5). In contrast, the reaction of 2a with phenylisocyanate afforded [Re(OC(O)NHPh)(CO)(3)(bipy)] (6); this results from formal PhNCO insertion into the O-H bond. On the other hand, compounds [Mo[SC(O)NH(p-tolyl)](eta(3)-C3H4-Me-2)(CO)(2)(phen)] (7), [Re[SC(O)NH(p-tolyl)](CO)(3)(Me-2-bipy)] (8a), and [Re[SC(O)NHEt](CO)(3)- (Me-2-bipy)] (8b) were obtained by reaction of I or 2b with the corresponding alkyl or aryl isothiocyanates. In those cases, RNCS was inserted into the M-O bond. The reactions of 1, 2a, and 2b with dimethyl acetylene dicarboxylate (DMAD) gave the complexes [Mo[C(OH)-C(CO2Me)C(CO2Me)-O]-(eta(3)-C3H4-Me-2)(CO)(phen)] (9) and [Re[C(OH)C(CO2Me)C(CO2Me)O](CO)(2)(N-N)] (N-N = bipy, 10 a; Me-2-bipy, 10b). The molecules of these compounds contain five-membered metallacycles that are the result of coupling between the hydroxo ligand, DMAD, and one of the CO ligands. The Dew compounds were characterized by a combination of IR and NMR spectroscopy, and for [(Re(CO)(3)(bipy)}(2)(mu-OH)]BF4 (3-BF4), 4, 5, 6, 7, 8b, 9, and 10b, also by means of single-crystal X-ray diffraction.

LanguageEnglish
Pages1765-1777
Number of pages13
JournalChemistry - A European Journal
Volume10
Issue number7
DOIs
Publication statusPublished - 2 Apr 2004

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Bridged-Ring Compounds
Rhenium
Acetylene
Molybdenum
Ligands
Isothiocyanates
Isocyanates
Acetaldehyde
Phenol
Urea
Nuclear magnetic resonance spectroscopy
Phenols
Infrared spectroscopy
Single crystals
X ray diffraction
Molecules

Keywords

  • carbonyl complexes
  • hydroxo complexes
  • insertion
  • molybdenum
  • rhenium
  • x-ray structures
  • aqueous solution
  • organometallic chemistry
  • crystal structures
  • amido complex

Cite this

Cuesta, L., Gerbino, D. C., Hevia, E., Morales, D., Clemente, M. E. N., Perez, J., ... Garcia-Granda, S. (2004). Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles. Chemistry - A European Journal, 10(7), 1765-1777. https://doi.org/10.1002/chem.200305577
Cuesta, L ; Gerbino, D C ; Hevia, E ; Morales, D ; Clemente, M E N ; Perez, J ; Riera, L ; Riera, V ; Miguel, D ; del Rio, I ; Garcia-Granda, S . / Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles. In: Chemistry - A European Journal. 2004 ; Vol. 10, No. 7. pp. 1765-1777.
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abstract = "The hydroxo compounds [Re(OH)(CO)(3)(N-N)] (N-N = bipy, 2a; Me-2-bipy, 2b) were prepared in a biphasic H2O/CH2Cl2 medium by reaction of [Re(OTf)(CO)(3)(N-N)] with KOH. In contrast, when anhydrous CH2Cl2 was used, the binuclear hydroxo-bridged compound [{Re(CO)(3)-(bipy)}(2)(mu-OH)]OTf (3-OTf) was obtained. Compound [Re(OH)(CO)(3)-(Me-2-bipy)] (2b) reacted with phenyl acetate or vinyl acetate to afford [Re(OAc)(CO)(3)(Me-2-bipy)] (4) and phenol or acetaldehyde, respectively. The reactions of [Mo(OH)(eta(3)- C3H4-Me-2)(CO)(2)(phen)] (1), 2a, and 2b toward several unsaturated organic electrophiles were studied. The reaction of 1 with (p-tolyl)isocyanate afforded an adduct of N,N'-di(p-tolyl)-urea and the carbonato-bridged compound [(Mo(eta(3)-C3H4-Me-2)(CO)(2)-(phen)}(2)(mu-eta(1)(O),eta(1)(O)-CO3)] (5). In contrast, the reaction of 2a with phenylisocyanate afforded [Re(OC(O)NHPh)(CO)(3)(bipy)] (6); this results from formal PhNCO insertion into the O-H bond. On the other hand, compounds [Mo[SC(O)NH(p-tolyl)](eta(3)-C3H4-Me-2)(CO)(2)(phen)] (7), [Re[SC(O)NH(p-tolyl)](CO)(3)(Me-2-bipy)] (8a), and [Re[SC(O)NHEt](CO)(3)- (Me-2-bipy)] (8b) were obtained by reaction of I or 2b with the corresponding alkyl or aryl isothiocyanates. In those cases, RNCS was inserted into the M-O bond. The reactions of 1, 2a, and 2b with dimethyl acetylene dicarboxylate (DMAD) gave the complexes [Mo[C(OH)-C(CO2Me)C(CO2Me)-O]-(eta(3)-C3H4-Me-2)(CO)(phen)] (9) and [Re[C(OH)C(CO2Me)C(CO2Me)O](CO)(2)(N-N)] (N-N = bipy, 10 a; Me-2-bipy, 10b). The molecules of these compounds contain five-membered metallacycles that are the result of coupling between the hydroxo ligand, DMAD, and one of the CO ligands. The Dew compounds were characterized by a combination of IR and NMR spectroscopy, and for [(Re(CO)(3)(bipy)}(2)(mu-OH)]BF4 (3-BF4), 4, 5, 6, 7, 8b, 9, and 10b, also by means of single-crystal X-ray diffraction.",
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Cuesta, L, Gerbino, DC, Hevia, E, Morales, D, Clemente, MEN, Perez, J, Riera, L, Riera, V, Miguel, D, del Rio, I & Garcia-Granda, S 2004, 'Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles' Chemistry - A European Journal, vol. 10, no. 7, pp. 1765-1777. https://doi.org/10.1002/chem.200305577

Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles. / Cuesta, L ; Gerbino, D C ; Hevia, E ; Morales, D ; Clemente, M E N ; Perez, J ; Riera, L ; Riera, V ; Miguel, D ; del Rio, I ; Garcia-Granda, S .

In: Chemistry - A European Journal, Vol. 10, No. 7, 02.04.2004, p. 1765-1777.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles

AU - Cuesta, L

AU - Gerbino, D C

AU - Hevia, E

AU - Morales, D

AU - Clemente, M E N

AU - Perez, J

AU - Riera, L

AU - Riera, V

AU - Miguel, D

AU - del Rio, I

AU - Garcia-Granda, S

PY - 2004/4/2

Y1 - 2004/4/2

N2 - The hydroxo compounds [Re(OH)(CO)(3)(N-N)] (N-N = bipy, 2a; Me-2-bipy, 2b) were prepared in a biphasic H2O/CH2Cl2 medium by reaction of [Re(OTf)(CO)(3)(N-N)] with KOH. In contrast, when anhydrous CH2Cl2 was used, the binuclear hydroxo-bridged compound [{Re(CO)(3)-(bipy)}(2)(mu-OH)]OTf (3-OTf) was obtained. Compound [Re(OH)(CO)(3)-(Me-2-bipy)] (2b) reacted with phenyl acetate or vinyl acetate to afford [Re(OAc)(CO)(3)(Me-2-bipy)] (4) and phenol or acetaldehyde, respectively. The reactions of [Mo(OH)(eta(3)- C3H4-Me-2)(CO)(2)(phen)] (1), 2a, and 2b toward several unsaturated organic electrophiles were studied. The reaction of 1 with (p-tolyl)isocyanate afforded an adduct of N,N'-di(p-tolyl)-urea and the carbonato-bridged compound [(Mo(eta(3)-C3H4-Me-2)(CO)(2)-(phen)}(2)(mu-eta(1)(O),eta(1)(O)-CO3)] (5). In contrast, the reaction of 2a with phenylisocyanate afforded [Re(OC(O)NHPh)(CO)(3)(bipy)] (6); this results from formal PhNCO insertion into the O-H bond. On the other hand, compounds [Mo[SC(O)NH(p-tolyl)](eta(3)-C3H4-Me-2)(CO)(2)(phen)] (7), [Re[SC(O)NH(p-tolyl)](CO)(3)(Me-2-bipy)] (8a), and [Re[SC(O)NHEt](CO)(3)- (Me-2-bipy)] (8b) were obtained by reaction of I or 2b with the corresponding alkyl or aryl isothiocyanates. In those cases, RNCS was inserted into the M-O bond. The reactions of 1, 2a, and 2b with dimethyl acetylene dicarboxylate (DMAD) gave the complexes [Mo[C(OH)-C(CO2Me)C(CO2Me)-O]-(eta(3)-C3H4-Me-2)(CO)(phen)] (9) and [Re[C(OH)C(CO2Me)C(CO2Me)O](CO)(2)(N-N)] (N-N = bipy, 10 a; Me-2-bipy, 10b). The molecules of these compounds contain five-membered metallacycles that are the result of coupling between the hydroxo ligand, DMAD, and one of the CO ligands. The Dew compounds were characterized by a combination of IR and NMR spectroscopy, and for [(Re(CO)(3)(bipy)}(2)(mu-OH)]BF4 (3-BF4), 4, 5, 6, 7, 8b, 9, and 10b, also by means of single-crystal X-ray diffraction.

AB - The hydroxo compounds [Re(OH)(CO)(3)(N-N)] (N-N = bipy, 2a; Me-2-bipy, 2b) were prepared in a biphasic H2O/CH2Cl2 medium by reaction of [Re(OTf)(CO)(3)(N-N)] with KOH. In contrast, when anhydrous CH2Cl2 was used, the binuclear hydroxo-bridged compound [{Re(CO)(3)-(bipy)}(2)(mu-OH)]OTf (3-OTf) was obtained. Compound [Re(OH)(CO)(3)-(Me-2-bipy)] (2b) reacted with phenyl acetate or vinyl acetate to afford [Re(OAc)(CO)(3)(Me-2-bipy)] (4) and phenol or acetaldehyde, respectively. The reactions of [Mo(OH)(eta(3)- C3H4-Me-2)(CO)(2)(phen)] (1), 2a, and 2b toward several unsaturated organic electrophiles were studied. The reaction of 1 with (p-tolyl)isocyanate afforded an adduct of N,N'-di(p-tolyl)-urea and the carbonato-bridged compound [(Mo(eta(3)-C3H4-Me-2)(CO)(2)-(phen)}(2)(mu-eta(1)(O),eta(1)(O)-CO3)] (5). In contrast, the reaction of 2a with phenylisocyanate afforded [Re(OC(O)NHPh)(CO)(3)(bipy)] (6); this results from formal PhNCO insertion into the O-H bond. On the other hand, compounds [Mo[SC(O)NH(p-tolyl)](eta(3)-C3H4-Me-2)(CO)(2)(phen)] (7), [Re[SC(O)NH(p-tolyl)](CO)(3)(Me-2-bipy)] (8a), and [Re[SC(O)NHEt](CO)(3)- (Me-2-bipy)] (8b) were obtained by reaction of I or 2b with the corresponding alkyl or aryl isothiocyanates. In those cases, RNCS was inserted into the M-O bond. The reactions of 1, 2a, and 2b with dimethyl acetylene dicarboxylate (DMAD) gave the complexes [Mo[C(OH)-C(CO2Me)C(CO2Me)-O]-(eta(3)-C3H4-Me-2)(CO)(phen)] (9) and [Re[C(OH)C(CO2Me)C(CO2Me)O](CO)(2)(N-N)] (N-N = bipy, 10 a; Me-2-bipy, 10b). The molecules of these compounds contain five-membered metallacycles that are the result of coupling between the hydroxo ligand, DMAD, and one of the CO ligands. The Dew compounds were characterized by a combination of IR and NMR spectroscopy, and for [(Re(CO)(3)(bipy)}(2)(mu-OH)]BF4 (3-BF4), 4, 5, 6, 7, 8b, 9, and 10b, also by means of single-crystal X-ray diffraction.

KW - carbonyl complexes

KW - hydroxo complexes

KW - insertion

KW - molybdenum

KW - rhenium

KW - x-ray structures

KW - aqueous solution

KW - organometallic chemistry

KW - crystal structures

KW - amido complex

U2 - 10.1002/chem.200305577

DO - 10.1002/chem.200305577

M3 - Article

VL - 10

SP - 1765

EP - 1777

JO - Chemistry - A European Journal

T2 - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 7

ER -