Reactive alkoxide complexes of groups 6 and 7 metals

E  Hevia; J  Perez; L  Riera; V  Riera; D  Miguel

doi:10.1021/om010977s

Reactive alkoxide complexes of groups 6 and 7 metals

E Hevia, J Perez, L Riera, V Riera, D Miguel

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

Original language	English
Pages (from-to)	1750-1752
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	9
DOIs	https://doi.org/10.1021/om010977s
Publication status	Published - 29 Apr 2002

Keywords

x-ray structure
carbon dioxide
oxygen bonds
carbanions

Access to Document

10.1021/om010977s

Cite this

@article{1a7c053e05e64331a842e5421bf97c1a,

title = "Reactive alkoxide complexes of groups 6 and 7 metals",

abstract = "Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.",

keywords = "x-ray structure, carbon dioxide , oxygen bonds, carbanions",

author = "E Hevia and J Perez and L Riera and V Riera and D Miguel",

year = "2002",

month = apr,

day = "29",

doi = "10.1021/om010977s",

language = "English",

volume = "21",

pages = "1750--1752",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Reactive alkoxide complexes of groups 6 and 7 metals

AU - Hevia, E

AU - Perez, J

AU - Riera, L

AU - Riera, V

AU - Miguel, D

PY - 2002/4/29

Y1 - 2002/4/29

N2 - Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

AB - Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

KW - x-ray structure

KW - carbon dioxide

KW - oxygen bonds

KW - carbanions

U2 - 10.1021/om010977s

DO - 10.1021/om010977s

M3 - Article

SN - 0276-7333

VL - 21

SP - 1750

EP - 1752

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Reactive alkoxide complexes of groups 6 and 7 metals

Abstract

Keywords

Access to Document

Fingerprint

Cite this