Reactive alkoxide complexes of groups 6 and 7 metals

E Hevia, J Perez, L Riera, V Riera, D Miguel

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

LanguageEnglish
Pages1750-1752
Number of pages3
JournalOrganometallics
Volume21
Issue number9
DOIs
Publication statusPublished - 29 Apr 2002

Fingerprint

alkoxides
Carbon Monoxide
insertion
Metals
metals
Ala(2)-enkephalinamide-met

Keywords

  • x-ray structure
  • carbon dioxide
  • oxygen bonds
  • carbanions

Cite this

Hevia, E., Perez, J., Riera, L., Riera, V., & Miguel, D. (2002). Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21(9), 1750-1752. https://doi.org/10.1021/om010977s
Hevia, E ; Perez, J ; Riera, L ; Riera, V ; Miguel, D . / Reactive alkoxide complexes of groups 6 and 7 metals. In: Organometallics. 2002 ; Vol. 21, No. 9. pp. 1750-1752.
@article{1a7c053e05e64331a842e5421bf97c1a,
title = "Reactive alkoxide complexes of groups 6 and 7 metals",
abstract = "Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.",
keywords = "x-ray structure, carbon dioxide , oxygen bonds, carbanions",
author = "E Hevia and J Perez and L Riera and V Riera and D Miguel",
year = "2002",
month = "4",
day = "29",
doi = "10.1021/om010977s",
language = "English",
volume = "21",
pages = "1750--1752",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "9",

}

Hevia, E, Perez, J, Riera, L, Riera, V & Miguel, D 2002, 'Reactive alkoxide complexes of groups 6 and 7 metals' Organometallics, vol. 21, no. 9, pp. 1750-1752. https://doi.org/10.1021/om010977s

Reactive alkoxide complexes of groups 6 and 7 metals. / Hevia, E ; Perez, J ; Riera, L ; Riera, V ; Miguel, D .

In: Organometallics, Vol. 21, No. 9, 29.04.2002, p. 1750-1752.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Reactive alkoxide complexes of groups 6 and 7 metals

AU - Hevia, E

AU - Perez, J

AU - Riera, L

AU - Riera, V

AU - Miguel, D

PY - 2002/4/29

Y1 - 2002/4/29

N2 - Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

AB - Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

KW - x-ray structure

KW - carbon dioxide

KW - oxygen bonds

KW - carbanions

U2 - 10.1021/om010977s

DO - 10.1021/om010977s

M3 - Article

VL - 21

SP - 1750

EP - 1752

JO - Organometallics

T2 - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 9

ER -

Hevia E, Perez J, Riera L, Riera V, Miguel D. Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics. 2002 Apr 29;21(9):1750-1752. https://doi.org/10.1021/om010977s