Reactive alkoxide complexes of groups 6 and 7 metals

E Hevia, J Perez, L Riera, V Riera, D Miguel

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36 Citations (Scopus)

Abstract

Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

Original languageEnglish
Pages (from-to)1750-1752
Number of pages3
JournalOrganometallics
Volume21
Issue number9
DOIs
Publication statusPublished - 29 Apr 2002

Keywords

  • x-ray structure
  • carbon dioxide
  • oxygen bonds
  • carbanions

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    Hevia, E., Perez, J., Riera, L., Riera, V., & Miguel, D. (2002). Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21(9), 1750-1752. https://doi.org/10.1021/om010977s