Abstract
| Language | English |
|---|---|
| Pages | 5835-5837 |
| Number of pages | 3 |
| Journal | Chemical Communications (London) |
| Volume | 2009 |
| Issue number | 39 |
| Early online date | 6 Aug 2009 |
| DOIs | |
| Publication status | Published - 2009 |
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Keywords
- (-)-sparteine
- alkali metal
- HMDS complexes
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Reactions of (-)-sparteine with alkali metal HMDS complexes : conventional meets the unconventional . / Clark, N.M.; Garcia-Alvarez, P.; Kennedy, A.R.; O'Hara, C.T.; Robertson, G.M.
In: Chemical Communications (London), Vol. 2009, No. 39, 2009, p. 5835-5837.Research output: Contribution to journal › Article
TY - JOUR
T1 - Reactions of (-)-sparteine with alkali metal HMDS complexes
T2 - Chemical Communications (London)
AU - Clark, N.M.
AU - Garcia-Alvarez, P.
AU - Kennedy, A.R.
AU - O'Hara, C.T.
AU - Robertson, G.M.
PY - 2009
Y1 - 2009
N2 - Conventional (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and unconventional hydroxyl-incorporated sodium sodiate, [(-)-sparteine·Na(-HMDS)Na·(-)-sparteine]+[Na4(-HMDS)4(OH)]--the complex anion of which is the first inverse crown ether anion.
AB - Conventional (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and unconventional hydroxyl-incorporated sodium sodiate, [(-)-sparteine·Na(-HMDS)Na·(-)-sparteine]+[Na4(-HMDS)4(OH)]--the complex anion of which is the first inverse crown ether anion.
KW - (-)-sparteine
KW - alkali metal
KW - HMDS complexes
U2 - 10.1039/b908722b
DO - 10.1039/b908722b
M3 - Article
VL - 2009
SP - 5835
EP - 5837
JO - Chemical Communications (London)
JF - Chemical Communications (London)
SN - 0009-241X
IS - 39
ER -