Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional

N.M. Clark, P. Garcia-Alvarez, A.R. Kennedy, C.T. O'Hara, G.M. Robertson

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Conventional (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and unconventional hydroxyl-incorporated sodium sodiate, [(-)-sparteine·Na(-HMDS)Na·(-)-sparteine]+[Na4(-HMDS)4(OH)]--the complex anion of which is the first inverse crown ether anion.
LanguageEnglish
Pages5835-5837
Number of pages3
JournalChemical Communications (London)
Volume2009
Issue number39
Early online date6 Aug 2009
DOIs
Publication statusPublished - 2009

Fingerprint

Sparteine
Alkali Metals
Anions
Sodium
Crown Ethers
Lithium
Hydroxyl Radical

Keywords

  • (-)-sparteine
  • alkali metal
  • HMDS complexes

Cite this

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abstract = "Conventional (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and unconventional hydroxyl-incorporated sodium sodiate, [(-)-sparteine·Na(-HMDS)Na·(-)-sparteine]+[Na4(-HMDS)4(OH)]--the complex anion of which is the first inverse crown ether anion.",
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Reactions of (-)-sparteine with alkali metal HMDS complexes : conventional meets the unconventional . / Clark, N.M.; Garcia-Alvarez, P.; Kennedy, A.R.; O'Hara, C.T.; Robertson, G.M.

In: Chemical Communications (London), Vol. 2009, No. 39, 2009, p. 5835-5837.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Reactions of (-)-sparteine with alkali metal HMDS complexes

T2 - Chemical Communications (London)

AU - Clark, N.M.

AU - Garcia-Alvarez, P.

AU - Kennedy, A.R.

AU - O'Hara, C.T.

AU - Robertson, G.M.

PY - 2009

Y1 - 2009

N2 - Conventional (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and unconventional hydroxyl-incorporated sodium sodiate, [(-)-sparteine·Na(-HMDS)Na·(-)-sparteine]+[Na4(-HMDS)4(OH)]--the complex anion of which is the first inverse crown ether anion.

AB - Conventional (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and unconventional hydroxyl-incorporated sodium sodiate, [(-)-sparteine·Na(-HMDS)Na·(-)-sparteine]+[Na4(-HMDS)4(OH)]--the complex anion of which is the first inverse crown ether anion.

KW - (-)-sparteine

KW - alkali metal

KW - HMDS complexes

U2 - 10.1039/b908722b

DO - 10.1039/b908722b

M3 - Article

VL - 2009

SP - 5835

EP - 5837

JO - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 39

ER -