Reactions of ammonium salts with butyllithium and with lithium hydride: new routes to fully anhydrous inorganic lithium complexes

D BARR, R SNAITH, D S WRIGHT, Robert Mulvey, K WADE

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Lithium halide complexes, (LiHalSxL),, L = a nonmacrocyclic
ligand, whether fully or partly ion-separated monomers, Li-
(L),+-Hal-, or intact oligomers, (LiHal),.(xL),,' often have
understandably low melting points and good solubility in organic
media.
LanguageEnglish
Pages7891-7893
Number of pages3
JournalJournal of the American Chemical Society
Volume109
Issue number25
DOIs
Publication statusPublished - 9 Dec 1987

Fingerprint

Ammonium Compounds
Lithium
Oligomers
Hydrides
Solubility
Freezing
Melting point
Salts
Monomers
Ligands
Ions
butyllithium

Keywords

  • butyllithium
  • lithium hydride
  • inorganic lithium complexes

Cite this

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abstract = "Lithium halide complexes, (LiHalSxL),, L = a nonmacrocyclic ligand, whether fully or partly ion-separated monomers, Li- (L),+-Hal-, or intact oligomers, (LiHal),.(xL),,' often have understandably low melting points and good solubility in organic media.",
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Reactions of ammonium salts with butyllithium and with lithium hydride: new routes to fully anhydrous inorganic lithium complexes. / BARR, D ; SNAITH, R ; WRIGHT, D S ; Mulvey, Robert; WADE, K .

In: Journal of the American Chemical Society, Vol. 109, No. 25, 09.12.1987, p. 7891-7893.

Research output: Contribution to journalArticle

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AU - BARR, D

AU - SNAITH, R

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AU - Mulvey, Robert

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AB - Lithium halide complexes, (LiHalSxL),, L = a nonmacrocyclic ligand, whether fully or partly ion-separated monomers, Li- (L),+-Hal-, or intact oligomers, (LiHal),.(xL),,' often have understandably low melting points and good solubility in organic media.

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KW - lithium hydride

KW - inorganic lithium complexes

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