Pushing the frontiers of hard and soft scorpionate chemistry

C.A. Dodds; A.R. Kennedy; J. Reglinski; M.D. Spicer

doi:10.1021/ic035167i

Pushing the frontiers of hard and soft scorpionate chemistry

C.A. Dodds, A.R. Kennedy, J. Reglinski, M.D. Spicer

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

Original language	English
Pages (from-to)	394-395
Number of pages	1
Journal	Inorganic Chemistry
Volume	43
Issue number	2
DOIs	https://doi.org/10.1021/ic035167i
Publication status	Published - 26 Jan 2004

Keywords

RAY CRYSTAL-STRUCTURES
TRIPODAL LIGANDS
COMPLEXES
DIHYDRATE
SODIUM
MODE

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10.1021/ic035167i

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title = "Pushing the frontiers of hard and soft scorpionate chemistry",

abstract = "The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.",

keywords = "RAY CRYSTAL-STRUCTURES, TRIPODAL LIGANDS, COMPLEXES, DIHYDRATE, SODIUM, MODE",

author = "C.A. Dodds and A.R. Kennedy and J. Reglinski and M.D. Spicer",

year = "2004",

month = jan,

day = "26",

doi = "10.1021/ic035167i",

language = "English",

volume = "43",

pages = "394--395",

journal = "Inorganic Chemistry",

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TY - JOUR

T1 - Pushing the frontiers of hard and soft scorpionate chemistry

AU - Dodds, C.A.

AU - Kennedy, A.R.

AU - Reglinski, J.

AU - Spicer, M.D.

PY - 2004/1/26

Y1 - 2004/1/26

N2 - The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

AB - The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

KW - RAY CRYSTAL-STRUCTURES

KW - TRIPODAL LIGANDS

KW - COMPLEXES

KW - DIHYDRATE

KW - SODIUM

KW - MODE

UR - http://pubs.acs.org/cgi-bin/article.cgi/inocaj/2004/43/i02/pdf/ic035167i.pdf

UR - http://dx.doi.org/10.1021/ic035167i

U2 - 10.1021/ic035167i

DO - 10.1021/ic035167i

M3 - Article

SN - 0020-1669

VL - 43

SP - 394

EP - 395

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

Pushing the frontiers of hard and soft scorpionate chemistry

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Keywords

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Pushing the frontiers of hard and soft scorpionate chemistry

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