Pushing the frontiers of hard and soft scorpionate chemistry

C.A. Dodds, A.R. Kennedy, J. Reglinski, M.D. Spicer

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.
LanguageEnglish
Pages394-395
Number of pages1
JournalInorganic Chemistry
Volume43
Issue number2
DOIs
Publication statusPublished - 26 Jan 2004

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Chalcogens
pushing
Conformations
chemistry
Ligands
Atoms
Geometry
preparation
ligands
geometry
atoms

Keywords

  • RAY CRYSTAL-STRUCTURES
  • TRIPODAL LIGANDS
  • COMPLEXES
  • DIHYDRATE
  • SODIUM
  • MODE

Cite this

Dodds, C.A. ; Kennedy, A.R. ; Reglinski, J. ; Spicer, M.D. / Pushing the frontiers of hard and soft scorpionate chemistry. In: Inorganic Chemistry. 2004 ; Vol. 43, No. 2. pp. 394-395.
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Pushing the frontiers of hard and soft scorpionate chemistry. / Dodds, C.A.; Kennedy, A.R.; Reglinski, J.; Spicer, M.D.

In: Inorganic Chemistry, Vol. 43, No. 2, 26.01.2004, p. 394-395.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Pushing the frontiers of hard and soft scorpionate chemistry

AU - Dodds, C.A.

AU - Kennedy, A.R.

AU - Reglinski, J.

AU - Spicer, M.D.

PY - 2004/1/26

Y1 - 2004/1/26

N2 - The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

AB - The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2) -Tm-Me)(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

KW - RAY CRYSTAL-STRUCTURES

KW - TRIPODAL LIGANDS

KW - COMPLEXES

KW - DIHYDRATE

KW - SODIUM

KW - MODE

UR - http://pubs.acs.org/cgi-bin/article.cgi/inocaj/2004/43/i02/pdf/ic035167i.pdf

UR - http://dx.doi.org/10.1021/ic035167i

U2 - 10.1021/ic035167i

DO - 10.1021/ic035167i

M3 - Article

VL - 43

SP - 394

EP - 395

JO - Inorganic Chemistry

T2 - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 2

ER -