Pressure-induced superelastic behaviour of isonicotinamide

Eleanor Jones; Suse S. Bebiano; Martin R. Ward; Luis M. Bimbo; Iain D.H. Oswald

doi:10.1039/D1CC04692F

Pressure-induced superelastic behaviour of isonicotinamide

Eleanor Jones, Suse S. Bebiano, Martin R. Ward, Luis M. Bimbo, Iain D.H. Oswald

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

39 Downloads (Pure)

Abstract

Dynamic organic crystals have come to the fore as potential lightweight alternatives to inorganic actuators providing high weight-to-force ratios. We have observed pressure-induced superelastic behaviour in Form I of isonicotinamide. The reversible single-crystal to single-crystal transformation exhibited by the system is an important component for functioning actuators. Crucially, our observations have enabled us to propose a mechanism for the molecular movement supported by Pixel energy calculations, that may pave the way for the future design and development of functioning dynamic crystals.

Original language	English
Pages (from-to)	11827-11830
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	89
Early online date	15 Oct 2021
DOIs	https://doi.org/10.1039/D1CC04692F
Publication status	Published - 18 Nov 2021

Keywords

isonicotinamide
hIgh-pressure
diffraction
Raman spectroscopy
superelasticity

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10.1039/D1CC04692FLicence: CC BY 4.0

Jones-etal-CC-2021-Pressure-induced-superelastic-behaviour-of-isonicotinamideFinal published version, 2.93 MBLicence: CC BY 4.0

Pressure-Induced Nucleation for the Continuous Manufacture of Supramolecular assemblies
Sefcik, J. (Co-investigator), Ter Horst, J. (Co-investigator) & Oswald, I. (Fellow)
EPSRC (Engineering and Physical Sciences Research Council)
1/06/16 → 30/11/22
Project: Research Fellowship

Data for: "Pressure-induced superelastic behaviour of isonicotinamide"
Jones, E. (Creator), Bebiano, S. V. (Data Collector), Ward, M. (Data Collector), Bimbo, L. (Other) & Oswald, I. (Supervisor), University of Strathclyde, 18 Oct 2021
DOI: 10.15129/4f1f2a57-88e4-40c0-863d-72674cf41490
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title = "Pressure-induced superelastic behaviour of isonicotinamide",

abstract = "Dynamic organic crystals have come to the fore as potential lightweight alternatives to inorganic actuators providing high weight-to-force ratios. We have observed pressure-induced superelastic behaviour in Form I of isonicotinamide. The reversible single-crystal to single-crystal transformation exhibited by the system is an important component for functioning actuators. Crucially, our observations have enabled us to propose a mechanism for the molecular movement supported by Pixel energy calculations, that may pave the way for the future design and development of functioning dynamic crystals.",

keywords = "isonicotinamide, hIgh-pressure, diffraction, Raman spectroscopy, superelasticity",

author = "Eleanor Jones and Bebiano, {Suse S.} and Ward, {Martin R.} and Bimbo, {Luis M.} and Oswald, {Iain D.H.}",

year = "2021",

month = nov,

day = "18",

doi = "10.1039/D1CC04692F",

language = "English",

volume = "57",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Pressure-induced superelastic behaviour of isonicotinamide

AU - Jones, Eleanor

AU - Bebiano, Suse S.

AU - Ward, Martin R.

AU - Bimbo, Luis M.

AU - Oswald, Iain D.H.

PY - 2021/11/18

Y1 - 2021/11/18

N2 - Dynamic organic crystals have come to the fore as potential lightweight alternatives to inorganic actuators providing high weight-to-force ratios. We have observed pressure-induced superelastic behaviour in Form I of isonicotinamide. The reversible single-crystal to single-crystal transformation exhibited by the system is an important component for functioning actuators. Crucially, our observations have enabled us to propose a mechanism for the molecular movement supported by Pixel energy calculations, that may pave the way for the future design and development of functioning dynamic crystals.

AB - Dynamic organic crystals have come to the fore as potential lightweight alternatives to inorganic actuators providing high weight-to-force ratios. We have observed pressure-induced superelastic behaviour in Form I of isonicotinamide. The reversible single-crystal to single-crystal transformation exhibited by the system is an important component for functioning actuators. Crucially, our observations have enabled us to propose a mechanism for the molecular movement supported by Pixel energy calculations, that may pave the way for the future design and development of functioning dynamic crystals.

KW - isonicotinamide

KW - hIgh-pressure

KW - diffraction

KW - Raman spectroscopy

KW - superelasticity

U2 - 10.1039/D1CC04692F

DO - 10.1039/D1CC04692F

M3 - Article

SN - 1359-7345

VL - 57

SP - 11827

EP - 11830

JO - Chemical Communications

JF - Chemical Communications

IS - 89

ER -

Pressure-induced superelastic behaviour of isonicotinamide

Abstract

Keywords

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Pressure-Induced Nucleation for the Continuous Manufacture of Supramolecular assemblies

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Data for: "Pressure-induced superelastic behaviour of isonicotinamide"

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