Preparation and reactions of functionalized arylmagnesium reagents

Anne Eeg Jensen; Wolfgang Dohle; Ioannis  Sapountzis; David M. Lindsay; Viet Anh  Vu; Paul  Knochel

doi:10.1055/s-2002-20955

Preparation and reactions of functionalized arylmagnesium reagents

Anne Eeg Jensen
, Wolfgang Dohle
, Ioannis Sapountzis
, David M. Lindsay
, Viet Anh Vu
, Paul Knochel

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

104 Citations (Scopus)

Abstract

Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.

Original language	English
Pages (from-to)	565-569
Number of pages	5
Journal	Synthesis
Volume	2002
Issue number	4
DOIs	https://doi.org/10.1055/s-2002-20955
Publication status	Published - 2002

Keywords

functionalized magnesium reagents
iodine-magnesium exchange
cross-coupling
palladium

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10.1055/s-2002-20955

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title = "Preparation and reactions of functionalized arylmagnesium reagents",

abstract = "Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.",

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author = "Jensen, \{Anne Eeg\} and Wolfgang Dohle and Ioannis Sapountzis and Lindsay, \{David M.\} and Vu, \{Viet Anh\} and Paul Knochel",

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T1 - Preparation and reactions of functionalized arylmagnesium reagents

AU - Jensen, Anne Eeg

AU - Dohle, Wolfgang

AU - Sapountzis , Ioannis

AU - Lindsay, David M.

AU - Vu, Viet Anh

AU - Knochel, Paul

PY - 2002

Y1 - 2002

N2 - Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.

AB - Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.

KW - functionalized magnesium reagents

KW - iodine-magnesium exchange

KW - cross-coupling

KW - palladium

U2 - 10.1055/s-2002-20955

DO - 10.1055/s-2002-20955

M3 - Article

SN - 0039-7881

VL - 2002

SP - 565

EP - 569

JO - Synthesis

JF - Synthesis

IS - 4

ER -

Preparation and reactions of functionalized arylmagnesium reagents

Abstract

Keywords

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