Preparation and crystal structure of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}]

A.R. Kennedy, R.J. Cross, K.W. Muir

Research output: Contribution to journalArticle

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Abstract

The synthesis of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}], Cy = cyclohexyl, and its characterisation by spectroscopy and single crystal X-ray analysis are described. The constraints imposed by the bulky terdentate ligand lead only to minor distortions of the square planar nickel(II) coordination (P---Ni---P = 161.6(1)°). The nickel coordination is compared with those found in related complexes with terdentate N- and P-donor ligands.
LanguageEnglish
Pages195-200
Number of pages5
JournalInorganica Chimica Acta
Volume231
Issue number1-2
DOIs
Publication statusPublished - 15 Mar 1995

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Nickel
Crystal structure
Ligands
nickel
preparation
ligands
crystal structure
X ray analysis
Single crystals
Spectroscopy
single crystals
synthesis
spectroscopy
crystals
x rays

Keywords

  • Crystal structures
  • Metallation
  • Nickel complexes
  • Organometallic complexes

Cite this

Kennedy, A.R. ; Cross, R.J. ; Muir, K.W. / Preparation and crystal structure of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}]. In: Inorganica Chimica Acta. 1995 ; Vol. 231, No. 1-2. pp. 195-200.
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Preparation and crystal structure of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}]. / Kennedy, A.R.; Cross, R.J.; Muir, K.W.

In: Inorganica Chimica Acta, Vol. 231, No. 1-2, 15.03.1995, p. 195-200.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Preparation and crystal structure of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}]

AU - Kennedy, A.R.

AU - Cross, R.J.

AU - Muir, K.W.

PY - 1995/3/15

Y1 - 1995/3/15

N2 - The synthesis of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}], Cy = cyclohexyl, and its characterisation by spectroscopy and single crystal X-ray analysis are described. The constraints imposed by the bulky terdentate ligand lead only to minor distortions of the square planar nickel(II) coordination (P---Ni---P = 161.6(1)°). The nickel coordination is compared with those found in related complexes with terdentate N- and P-donor ligands.

AB - The synthesis of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}], Cy = cyclohexyl, and its characterisation by spectroscopy and single crystal X-ray analysis are described. The constraints imposed by the bulky terdentate ligand lead only to minor distortions of the square planar nickel(II) coordination (P---Ni---P = 161.6(1)°). The nickel coordination is compared with those found in related complexes with terdentate N- and P-donor ligands.

KW - Crystal structures

KW - Metallation

KW - Nickel complexes

KW - Organometallic complexes

UR - http://dx.doi.org/10.1016/0020-1693(94)04321-L

U2 - 10.1016/0020-1693(94)04321-L

DO - 10.1016/0020-1693(94)04321-L

M3 - Article

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T2 - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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