Preparation and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation: modulated chemistry resulting from the use of soft and hard tripodal ligands

P.A. Slavin, J. Reglinski, M.D. Spicer, A.R. Kennedy

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Abstract

The synthesis and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation is reported, in which the thallium ion is co-ordinated by six sulfur thione donors in a regular octahedral environment.
Original languageEnglish
Pages (from-to)239-240
Number of pages1
JournalJournal of the Chemical Society, Dalton Transactions
Volume2000
Issue number3
DOIs
Publication statusPublished - 26 Jan 2000

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Thallium
Cations
Crystal structure
Ligands
Thiones
Sulfur
Ions

Keywords

  • crystal structure
  • thallium
  • ion
  • octahedral environment

Cite this

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title = "Preparation and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation: modulated chemistry resulting from the use of soft and hard tripodal ligands",
abstract = "The synthesis and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation is reported, in which the thallium ion is co-ordinated by six sulfur thione donors in a regular octahedral environment.",
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T1 - Preparation and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation: modulated chemistry resulting from the use of soft and hard tripodal ligands

AU - Slavin, P.A.

AU - Reglinski, J.

AU - Spicer, M.D.

AU - Kennedy, A.R.

PY - 2000/1/26

Y1 - 2000/1/26

N2 - The synthesis and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation is reported, in which the thallium ion is co-ordinated by six sulfur thione donors in a regular octahedral environment.

AB - The synthesis and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation is reported, in which the thallium ion is co-ordinated by six sulfur thione donors in a regular octahedral environment.

KW - crystal structure

KW - thallium

KW - ion

KW - octahedral environment

UR - http://dx.doi.org/10.1039/a908236k

U2 - 10.1039/a908236k

DO - 10.1039/a908236k

M3 - Article

VL - 2000

SP - 239

EP - 240

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 0300-9246

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ER -