Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine

W. Clegg; L. Horsburgh; Robert Mulvey; M.J. Ross

doi:10.1039/C39940002393

Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine

W. Clegg, L. Horsburgh, Robert Mulvey, M.J. Ross

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The first potassio triazine to be isolated and structurally characterised by X-ray diffraction exhibits an infinite, zig-zag, N-K propagated chain arrangement of alternating K+ cations and [(R(2)K)-] complex anions; the manner of its association sheds new light on why selected lithio alkyltriazines spontaneously dealkylate.

Original language	English
Pages (from-to)	2393-2394
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1994
Issue number	20
DOIs	https://doi.org/10.1039/C39940002393
Publication status	Published - 21 Oct 1994

Keywords

nitriles
potassium potassiate
ions
dihydrotriazine

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10.1039/C39940002393

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title = "Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine",

abstract = "The first potassio triazine to be isolated and structurally characterised by X-ray diffraction exhibits an infinite, zig-zag, N-K propagated chain arrangement of alternating K+ cations and [(R(2)K)-] complex anions; the manner of its association sheds new light on why selected lithio alkyltriazines spontaneously dealkylate.",

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T1 - Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine

AU - Clegg, W.

AU - Horsburgh, L.

AU - Mulvey, Robert

AU - Ross, M.J.

PY - 1994/10/21

Y1 - 1994/10/21

N2 - The first potassio triazine to be isolated and structurally characterised by X-ray diffraction exhibits an infinite, zig-zag, N-K propagated chain arrangement of alternating K+ cations and [(R(2)K)-] complex anions; the manner of its association sheds new light on why selected lithio alkyltriazines spontaneously dealkylate.

AB - The first potassio triazine to be isolated and structurally characterised by X-ray diffraction exhibits an infinite, zig-zag, N-K propagated chain arrangement of alternating K+ cations and [(R(2)K)-] complex anions; the manner of its association sheds new light on why selected lithio alkyltriazines spontaneously dealkylate.

KW - nitriles

KW - potassium potassiate

KW - ions

KW - dihydrotriazine

U2 - 10.1039/C39940002393

DO - 10.1039/C39940002393

M3 - Article

SN - 0022-4936

VL - 1994

SP - 2393

EP - 2394

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 20

ER -

Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine

Abstract

Keywords

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