Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine

W. Clegg, L. Horsburgh, Robert Mulvey, M.J. Ross

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The first potassio triazine to be isolated and structurally characterised by X-ray diffraction exhibits an infinite, zig-zag, N-K propagated chain arrangement of alternating K+ cations and [(R(2)K)-] complex anions; the manner of its association sheds new light on why selected lithio alkyltriazines spontaneously dealkylate.

LanguageEnglish
Pages2393-2394
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume1994
Issue number20
DOIs
Publication statusPublished - 21 Oct 1994

Fingerprint

Triazines
X-Ray Diffraction
Anions
Cations
Potassium
Polymers
Ions

Keywords

  • nitriles
  • potassium potassiate
  • ions
  • dihydrotriazine

Cite this

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Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine. / Clegg, W.; Horsburgh, L.; Mulvey, Robert; Ross, M.J.

In: Journal of the Chemical Society, Chemical Communications, Vol. 1994, No. 20, 21.10.1994, p. 2393-2394.

Research output: Contribution to journalArticle

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AU - Horsburgh, L.

AU - Mulvey, Robert

AU - Ross, M.J.

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AB - The first potassio triazine to be isolated and structurally characterised by X-ray diffraction exhibits an infinite, zig-zag, N-K propagated chain arrangement of alternating K+ cations and [(R(2)K)-] complex anions; the manner of its association sheds new light on why selected lithio alkyltriazines spontaneously dealkylate.

KW - nitriles

KW - potassium potassiate

KW - ions

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U2 - 10.1039/C39940002393

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