Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

William Clegg; Ben Conway; Pablo García-Álvarez; Alan R. Kennedy; Jan Klett; Robert E. Mulvey; Luca Russo

doi:10.1039/b917202p

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

William Clegg, Ben Conway, Pablo García-Álvarez, Alan R. Kennedy, Jan Klett, Robert E. Mulvey, Luca Russo

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

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Abstract

Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

Original language	English
Pages (from-to)	62-65
Number of pages	3
Journal	Dalton Transactions
Volume	39
Early online date	30 Sept 2009
DOIs	https://doi.org/10.1039/b917202p
Publication status	Published - 2010

Keywords

potassium-mediated zincation
ferrocene
ruthenocene
potassium
supramolecular variations

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10.1039/b917202p

strathprints027630.pdfAccepted author manuscript, 320 KB

Cite this

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title = "Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations",

abstract = "Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.",

keywords = "potassium-mediated zincation, ferrocene, ruthenocene, potassium, supramolecular variations",

author = "William Clegg and Ben Conway and Pablo Garc{\'i}a-{\'A}lvarez and Kennedy, {Alan R.} and Jan Klett and Mulvey, {Robert E.} and Luca Russo",

year = "2010",

doi = "10.1039/b917202p",

language = "English",

volume = "39",

pages = "62--65",

journal = "Dalton Transactions",

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T1 - Potassium-mediated zincation of ferrocene and ruthenocene

T2 - potassium, the architect behind supramolecular structural variations

AU - Clegg, William

AU - Conway, Ben

AU - García-Álvarez, Pablo

AU - Kennedy, Alan R.

AU - Klett, Jan

AU - Mulvey, Robert E.

AU - Russo, Luca

PY - 2010

Y1 - 2010

N2 - Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

AB - Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

KW - potassium-mediated zincation

KW - ferrocene

KW - ruthenocene

KW - potassium

KW - supramolecular variations

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U2 - 10.1039/b917202p

DO - 10.1039/b917202p

M3 - Article

SN - 1472-7773

VL - 39

SP - 62

EP - 65

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

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Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

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