Abstract
| Language | English |
|---|---|
| Pages | 62-65 |
| Number of pages | 3 |
| Journal | Dalton Transactions |
| Volume | 39 |
| DOIs | |
| Publication status | Published - 2010 |
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Keywords
- potassium-mediated zincation
- ferrocene
- ruthenocene
- potassium
- supramolecular variations
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Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations. / Mulvey, R.E.; Kennedy, A.R.; Klett, J.; Garcia-Alvarez, P.
In: Dalton Transactions, Vol. 39, 2010, p. 62-65.Research output: Contribution to journal › Article
TY - JOUR
T1 - Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations
AU - Mulvey, R.E.
AU - Kennedy, A.R.
AU - Klett, J.
AU - Garcia-Alvarez, P.
PY - 2010
Y1 - 2010
N2 - Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.
AB - Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.
KW - potassium-mediated zincation
KW - ferrocene
KW - ruthenocene
KW - potassium
KW - supramolecular variations
UR - http://www.scopus.com/inward/record.url?scp=72149090159&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1039/b917202p
U2 - 10.1039/b917202p
DO - 10.1039/b917202p
M3 - Article
VL - 39
SP - 62
EP - 65
JO - Dalton Transactions
T2 - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
ER -