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Abstract
Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.
Original language | English |
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Pages (from-to) | 62-65 |
Number of pages | 3 |
Journal | Dalton Transactions |
Volume | 39 |
DOIs | |
Publication status | Published - 2010 |
Keywords
- potassium-mediated zincation
- ferrocene
- ruthenocene
- potassium
- supramolecular variations
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Projects
- 1 Finished