Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

R.E. Mulvey, A.R. Kennedy, J. Klett, P. Garcia-Alvarez

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.
LanguageEnglish
Pages62-65
Number of pages3
JournalDalton Transactions
Volume39
DOIs
Publication statusPublished - 2010

Fingerprint

Thymidine Monophosphate
Potassium
ruthenocene
ferrocene

Keywords

  • potassium-mediated zincation
  • ferrocene
  • ruthenocene
  • potassium
  • supramolecular variations

Cite this

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Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations. / Mulvey, R.E.; Kennedy, A.R.; Klett, J.; Garcia-Alvarez, P.

In: Dalton Transactions, Vol. 39, 2010, p. 62-65.

Research output: Contribution to journalArticle

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AU - Kennedy, A.R.

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AU - Garcia-Alvarez, P.

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AB - Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

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KW - ferrocene

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