Potassium-alkyl magnesiates: synthesis, structures and Mg-H exchange applications of aromatic and heterocyclic substrates

Sharon E. Baillie, Tobias D. Bluemke, William Clegg, Alan R. Kennedy, Jan Klett, Luca Russo, Marco De Tullio, Eva Hevia

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Using structurally well-defined dipotassium- tetra(alkyl)magnesiates, a new straightforward methodology to promote regioselective Mg-H exchange reactions of a wide range of aromatic and heteroaromatic substrates is disclosed. Contacted ion pair intermediates are likely to be involved, with K being the key to facilitate the magnesiation processes.
LanguageEnglish
Pages12859-12862
Number of pages4
JournalChemical Communications
Volume50
Early online date3 Sep 2014
DOIs
Publication statusPublished - 3 Sep 2014

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Potassium
Ion exchange
Ions
Substrates

Keywords

  • dipotassium-tetra(alkyl)magnesiates
  • Mg–H exchange reactions
  • heteroaromatic substrates

Cite this

Baillie, Sharon E. ; Bluemke, Tobias D. ; Clegg, William ; Kennedy, Alan R. ; Klett, Jan ; Russo, Luca ; De Tullio, Marco ; Hevia, Eva. / Potassium-alkyl magnesiates : synthesis, structures and Mg-H exchange applications of aromatic and heterocyclic substrates. In: Chemical Communications. 2014 ; Vol. 50. pp. 12859-12862.
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Potassium-alkyl magnesiates : synthesis, structures and Mg-H exchange applications of aromatic and heterocyclic substrates. / Baillie, Sharon E.; Bluemke, Tobias D.; Clegg, William; Kennedy, Alan R.; Klett, Jan; Russo, Luca; De Tullio, Marco; Hevia, Eva.

In: Chemical Communications, Vol. 50, 03.09.2014, p. 12859-12862.

Research output: Contribution to journalArticle

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T1 - Potassium-alkyl magnesiates

T2 - Chemical Communications

AU - Baillie, Sharon E.

AU - Bluemke, Tobias D.

AU - Clegg, William

AU - Kennedy, Alan R.

AU - Klett, Jan

AU - Russo, Luca

AU - De Tullio, Marco

AU - Hevia, Eva

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KW - Mg–H exchange reactions

KW - heteroaromatic substrates

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