Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis

O B Sutcliffe, M R Bryce

Research output: Contribution to journalArticle

166 Citations (Scopus)

Abstract

The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.

LanguageEnglish
Pages2297-2325
Number of pages29
JournalTetrahedron: Asymmetry
Volume14
Issue number16
DOIs
Publication statusPublished - 15 Aug 2003

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ferrocenes
Catalysis
catalysis
reactivity
synthesis

Keywords

  • diastereoselective ortho-lithiation
  • cross-coupling reactions
  • phosphine hybrid ligand
  • allylic substitution
  • ferrocenyl-oxazoline
  • phenyl transfer
  • diphenylphosphino(oxazolinyl)ferrocene ligands
  • 1,1'-P,N-ferrocene ligands
  • transfer hydrogenation
  • P,N-ferrocene ligands

Cite this

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title = "Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis",
abstract = "The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.",
keywords = "diastereoselective ortho-lithiation, cross-coupling reactions, phosphine hybrid ligand, allylic substitution, ferrocenyl-oxazoline, phenyl transfer, diphenylphosphino(oxazolinyl)ferrocene ligands, 1,1'-P,N-ferrocene ligands, transfer hydrogenation, P,N-ferrocene ligands",
author = "Sutcliffe, {O B} and Bryce, {M R}",
year = "2003",
month = "8",
day = "15",
doi = "10.1016/S0957-4166(03)00520-2",
language = "English",
volume = "14",
pages = "2297--2325",
journal = "Tetrahedron: Asymmetry",
issn = "1362-511X",
number = "16",

}

Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis. / Sutcliffe, O B ; Bryce, M R .

In: Tetrahedron: Asymmetry, Vol. 14, No. 16, 15.08.2003, p. 2297-2325.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis

AU - Sutcliffe, O B

AU - Bryce, M R

PY - 2003/8/15

Y1 - 2003/8/15

N2 - The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.

AB - The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.

KW - diastereoselective ortho-lithiation

KW - cross-coupling reactions

KW - phosphine hybrid ligand

KW - allylic substitution

KW - ferrocenyl-oxazoline

KW - phenyl transfer

KW - diphenylphosphino(oxazolinyl)ferrocene ligands

KW - 1,1'-P,N-ferrocene ligands

KW - transfer hydrogenation

KW - P,N-ferrocene ligands

U2 - 10.1016/S0957-4166(03)00520-2

DO - 10.1016/S0957-4166(03)00520-2

M3 - Article

VL - 14

SP - 2297

EP - 2325

JO - Tetrahedron: Asymmetry

T2 - Tetrahedron: Asymmetry

JF - Tetrahedron: Asymmetry

SN - 1362-511X

IS - 16

ER -