Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis

O B  Sutcliffe; M R  Bryce

doi:10.1016/S0957-4166(03)00520-2

Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis

O B Sutcliffe, M R Bryce

Strathclyde Institute Of Pharmacy And Biomedical Sciences

Research output: Contribution to journal › Article › peer-review

181 Citations (Scopus)

Abstract

The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.

Original language	English
Pages (from-to)	2297-2325
Number of pages	29
Journal	Tetrahedron: Asymmetry
Volume	14
Issue number	16
DOIs	https://doi.org/10.1016/S0957-4166(03)00520-2
Publication status	Published - 15 Aug 2003

Keywords

diastereoselective ortho-lithiation
cross-coupling reactions
phosphine hybrid ligand
allylic substitution
ferrocenyl-oxazoline
phenyl transfer
diphenylphosphino(oxazolinyl)ferrocene ligands
1,1'-P,N-ferrocene ligands
transfer hydrogenation
P,N-ferrocene ligands

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10.1016/S0957-4166(03)00520-2

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title = "Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis",

abstract = "The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.",

keywords = "diastereoselective ortho-lithiation, cross-coupling reactions, phosphine hybrid ligand, allylic substitution, ferrocenyl-oxazoline, phenyl transfer, diphenylphosphino(oxazolinyl)ferrocene ligands, 1,1'-P,N-ferrocene ligands, transfer hydrogenation, P,N-ferrocene ligands",

author = "Sutcliffe, {O B} and Bryce, {M R}",

year = "2003",

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day = "15",

doi = "10.1016/S0957-4166(03)00520-2",

language = "English",

volume = "14",

pages = "2297--2325",

journal = "Tetrahedron: Asymmetry",

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T1 - Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis

AU - Sutcliffe, O B

AU - Bryce, M R

PY - 2003/8/15

Y1 - 2003/8/15

N2 - The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.

AB - The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.

KW - diastereoselective ortho-lithiation

KW - cross-coupling reactions

KW - phosphine hybrid ligand

KW - allylic substitution

KW - ferrocenyl-oxazoline

KW - phenyl transfer

KW - diphenylphosphino(oxazolinyl)ferrocene ligands

KW - 1,1'-P,N-ferrocene ligands

KW - transfer hydrogenation

KW - P,N-ferrocene ligands

U2 - 10.1016/S0957-4166(03)00520-2

DO - 10.1016/S0957-4166(03)00520-2

M3 - Article

SN - 0957-4166

VL - 14

SP - 2297

EP - 2325

JO - Tetrahedron: Asymmetry

JF - Tetrahedron: Asymmetry

IS - 16

ER -

Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis

Abstract

Keywords

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