Photocrystallisation of the 2C-2′C dimer of a triphenylimidazolyl radical

Robert M. Edkins; Michael R. Probert; Craig M.  Robertson; Judith A.K. Howard; Andrew Beeby

doi:10.1039/c3ra43892a

Photocrystallisation of the 2C-2′C dimer of a triphenylimidazolyl radical

Robert M. Edkins
, Michael R. Probert
, Craig M. Robertson
, Judith A.K. Howard
, Andrew Beeby^*

^*Corresponding author for this work

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The structure of an unusual dimerisation mode of a triphenylimidazolyl radical has been elucidated, revealing a relatively long C-C bond. The diffraction-quality single crystals were produced under continuous irradiation by photocrystallisation in an adaption of the method that should be widely applicable to other photochromic systems.

Original language	English
Pages (from-to)	5351-5356
Number of pages	6
Journal	RSC Advances
Volume	4
Issue number	11
DOIs	https://doi.org/10.1039/c3ra43892a
Publication status	Published - 17 Jan 2014

Keywords

triphenylimidazolyl radical
photocrystallisation

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10.1039/c3ra43892a

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title = "Photocrystallisation of the 2C-2′C dimer of a triphenylimidazolyl radical",

abstract = "The structure of an unusual dimerisation mode of a triphenylimidazolyl radical has been elucidated, revealing a relatively long C-C bond. The diffraction-quality single crystals were produced under continuous irradiation by photocrystallisation in an adaption of the method that should be widely applicable to other photochromic systems.",

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AU - Edkins, Robert M.

AU - Probert, Michael R.

AU - Robertson, Craig M.

AU - Howard, Judith A.K.

AU - Beeby, Andrew

PY - 2014/1/17

Y1 - 2014/1/17

N2 - The structure of an unusual dimerisation mode of a triphenylimidazolyl radical has been elucidated, revealing a relatively long C-C bond. The diffraction-quality single crystals were produced under continuous irradiation by photocrystallisation in an adaption of the method that should be widely applicable to other photochromic systems.

AB - The structure of an unusual dimerisation mode of a triphenylimidazolyl radical has been elucidated, revealing a relatively long C-C bond. The diffraction-quality single crystals were produced under continuous irradiation by photocrystallisation in an adaption of the method that should be widely applicable to other photochromic systems.

KW - triphenylimidazolyl radical

KW - photocrystallisation

UR - https://www.scopus.com/pages/publications/84892172066

U2 - 10.1039/c3ra43892a

DO - 10.1039/c3ra43892a

M3 - Article

AN - SCOPUS:84892172066

SN - 2046-2069

VL - 4

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EP - 5356

JO - RSC Advances

JF - RSC Advances

IS - 11

ER -

Photocrystallisation of the 2C-2′C dimer of a triphenylimidazolyl radical

Abstract

Keywords

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