Abstract
This chapter explores various aspects of perovskite nonstoichiometry and defect chemistry, including the means through which different defects are accommodated by the perovskite crystal structure and the effect they exert on properties. The chapter also demonstrates that defect chemistry not only can serve as an additional tool for tailoring well-established material properties but also could give rise to completely new, unique, and potentially useful properties.
Original language | English |
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Title of host publication | Comprehensive Inorganic Chemistry II (Second Edition) |
Subtitle of host publication | From Elements to Applications |
Pages | 397-415 |
Number of pages | 19 |
Volume | 4 |
Edition | 2 |
DOIs | |
Publication status | Published - 1 Aug 2013 |
Keywords
- defect chemistry
- electronic conductivity
- exsolutions
- octahedral tilting
- oxide ion mobility
- perovskite
- perovskite structure
- SrTiO