Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

S. E. Walker; C. J. C. Lamb; N. A. Beattie; P. Nikodemiak; Ai -Lan Lee

doi:10.1039/C5CC00407A

Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

S. E. Walker, C. J. C. Lamb, N. A. Beattie, P. Nikodemiak, Ai -Lan Lee

Pure And Applied Chemistry

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Abstract

Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

Original language	English
Pages (from-to)	4089-4092
Number of pages	4
Journal	Chemical Communications
Volume	51
Early online date	3 Feb 2015
DOIs	https://doi.org/10.1039/C5CC00407A
Publication status	Published - 7 Mar 2015

Keywords

Oxidative Heck
cyclopentene

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Walker-etal-CC2015-Oxidative-Heck-desymmetrisation-of-2-2-disubstitutedFinal published version, 1.91 MBLicence: CC BY 3.0

Cite this

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title = "Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones",

abstract = "Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres. ",

keywords = "Oxidative Heck, cyclopentene",

author = "Walker, {S. E.} and Lamb, {C. J. C.} and Beattie, {N. A.} and P. Nikodemiak and Lee, {Ai -Lan}",

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language = "English",

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AU - Walker, S. E.

AU - Lamb, C. J. C.

AU - Beattie, N. A.

AU - Nikodemiak, P.

AU - Lee, Ai -Lan

PY - 2015/3/7

Y1 - 2015/3/7

N2 - Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

AB - Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

KW - Oxidative Heck

KW - cyclopentene

U2 - 10.1039/C5CC00407A

DO - 10.1039/C5CC00407A

M3 - Article

SN - 1359-7345

VL - 51

SP - 4089

EP - 4092

JO - Chemical Communications

JF - Chemical Communications

ER -

Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

Abstract

Keywords

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