Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

S. E. Walker, C. J. C. Lamb, N. A. Beattie, P. Nikodemiak, Ai -Lan Lee

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.
LanguageEnglish
Pages4089-4092
Number of pages4
JournalChemical Communications
Volume51
Early online date3 Feb 2015
DOIs
Publication statusPublished - 7 Mar 2015

Fingerprint

Cyclopentanes
Carbon

Keywords

  • Oxidative Heck
  • cyclopentene

Cite this

Walker, S. E. ; Lamb, C. J. C. ; Beattie, N. A. ; Nikodemiak, P. ; Lee, Ai -Lan. / Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones. In: Chemical Communications. 2015 ; Vol. 51. pp. 4089-4092.
@article{e4c389ea1311444abae0bbd72958c37d,
title = "Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones",
abstract = "Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.",
keywords = "Oxidative Heck, cyclopentene",
author = "Walker, {S. E.} and Lamb, {C. J. C.} and Beattie, {N. A.} and P. Nikodemiak and Lee, {Ai -Lan}",
year = "2015",
month = "3",
day = "7",
doi = "10.1039/C5CC00407A",
language = "English",
volume = "51",
pages = "4089--4092",
journal = "Chemical Communications",
issn = "1359-7345",

}

Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones. / Walker, S. E.; Lamb, C. J. C.; Beattie, N. A.; Nikodemiak, P.; Lee, Ai -Lan.

In: Chemical Communications, Vol. 51, 07.03.2015, p. 4089-4092.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

AU - Walker, S. E.

AU - Lamb, C. J. C.

AU - Beattie, N. A.

AU - Nikodemiak, P.

AU - Lee, Ai -Lan

PY - 2015/3/7

Y1 - 2015/3/7

N2 - Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

AB - Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

KW - Oxidative Heck

KW - cyclopentene

U2 - 10.1039/C5CC00407A

DO - 10.1039/C5CC00407A

M3 - Article

VL - 51

SP - 4089

EP - 4092

JO - Chemical Communications

T2 - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

ER -