Organics adsorption on novel amorphous silica and silica xerogels

microcolumn rapid breakthrough test coupled with sequential injection analysis

Andrea Luca Tasca, Ashleigh J. Fletcher, Farnaz Ghajeri, Fernando Maya Alejandro, Gemma Turnes Palomino

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The adsorption capacities of a novel amorphous silica and silica xerogels for aromatic compounds were investigated using microcolumn rapid breakthrough tests coupled with sequential injection flow-based automated instrumentation in order to evaluate their operative feasibility under conditions typically used in water treatment facilities. Extraction columns were fabricated using stereolithographic 3D printing. Sorbent reusability was also investigated using automated flow-based techniques. Benzene was selected as the target dissolved organic compound usually present in produced waters from the oil and gas sector, continuously increasing. 3,4-Dichloroaniline (3,4-DCA) was selected as part of the endocrine disrupting chemicals, which are becoming a source of major concern for human and wildlife toxicity. Novel amorphous silicas were synthesized at low temperature and under ambient pressure from a sodium metasilicate precursor and were subjected to postsynthetic methylation. Silica xerogels were prepared via acid catalysis of a sodium metasilicate solution and functionalized with trimethylchlorosilane at low temperature and under ambient pressure. The removal efficiency of the silica xerogels tested was found to be equal to or greater than 22.62 mg/g for benzene at a flow rate of 0.6 mL/min, while the uptake of 3,4-DCA was found to be > 4.63 and > 7.17 mg/g, respectively, at flow rates of 1.8 and 0.6 mL/min.

Original languageEnglish
Pages (from-to)1001-1014
Number of pages14
JournalJournal of Porous Media
Volume22
Issue number8
DOIs
Publication statusPublished - 12 May 2019

Fingerprint

Xerogels
xerogels
Silica
Adsorption
Silicon Dioxide
Injection
injection
silicon dioxide
adsorption
Benzene
Sodium
Flow Rate
flow velocity
wildlife
benzene
Flow rate
sodium
Water
Endocrine Disruptors
disrupting

Keywords

  • 3,4-DCA
  • 3D printing
  • benzene
  • breakthrough curves
  • EDCs
  • SIA

Cite this

Tasca, Andrea Luca ; Fletcher, Ashleigh J. ; Ghajeri, Farnaz ; Alejandro, Fernando Maya ; Palomino, Gemma Turnes. / Organics adsorption on novel amorphous silica and silica xerogels : microcolumn rapid breakthrough test coupled with sequential injection analysis. In: Journal of Porous Media. 2019 ; Vol. 22, No. 8. pp. 1001-1014.
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Organics adsorption on novel amorphous silica and silica xerogels : microcolumn rapid breakthrough test coupled with sequential injection analysis. / Tasca, Andrea Luca; Fletcher, Ashleigh J.; Ghajeri, Farnaz; Alejandro, Fernando Maya; Palomino, Gemma Turnes.

In: Journal of Porous Media, Vol. 22, No. 8, 12.05.2019, p. 1001-1014.

Research output: Contribution to journalArticle

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