Optimizing infrared to near infrared upconversion quantum yield of β-NaYF4:Er3+ in fluoropolymer matrix for photovoltaic devices

Aruna Ivaturi, Sean K. W. MacDougall, Rosa Martín-Rodríguez, Marta Quintanilla, Jose Marques-Hueso, Karl W. Krämer, Andries Meijerink, Bryce S. Richards

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

The present study reports for the first time the optimization of the infrared (1523 nm) to near-infrared (980 nm) upconversion quantum yield (UC-QY) of hexagonal trivalent erbium doped sodium yttrium fluoride (β-NaYF 4:Er3+) in a perfluorocyclobutane (PFCB) host matrix under monochromatic excitation. Maximum internal and external UC-QYs of 8.4% ± 0.8% and 6.5% ± 0.7%, respectively, have been achieved for 1523 nm excitation of 970 ± 43 Wm-2 for an optimum Er3+ concentration of 25 mol% and a phosphor concentration of 84.9 w/w% in the matrix. These results correspond to normalized internal and external efficiencies of 0.86 ± 0.12 cm2 W-1 and 0.67 ± 0.10 cm2 W-1, respectively. These are the highest values ever reported for β-NaYF4:Er3+ under monochromatic excitation. The special characteristics of both the UC phosphor β-NaYF4:Er3+ and the PFCB matrix give rise to this outstanding property. Detailed power and time dependent luminescence measurements reveal energy transfer upconversion as the dominant UC mechanism.

Original languageEnglish
Article number013505
Number of pages9
JournalJournal of Applied Physics
Volume114
Issue number1
DOIs
Publication statusPublished - 7 Jul 2013

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fluoropolymers
phosphors
matrices
excitation
yttrium
erbium
fluorides
energy transfer
sodium
luminescence
optimization

Keywords

  • doping
  • phosphors
  • photons
  • absorption spectra
  • powders

Cite this

Ivaturi, A., MacDougall, S. K. W., Martín-Rodríguez, R., Quintanilla, M., Marques-Hueso, J., Krämer, K. W., ... Richards, B. S. (2013). Optimizing infrared to near infrared upconversion quantum yield of β-NaYF4:Er3+ in fluoropolymer matrix for photovoltaic devices. Journal of Applied Physics, 114(1), [013505]. https://doi.org/10.1063/1.4812578
Ivaturi, Aruna ; MacDougall, Sean K. W. ; Martín-Rodríguez, Rosa ; Quintanilla, Marta ; Marques-Hueso, Jose ; Krämer, Karl W. ; Meijerink, Andries ; Richards, Bryce S. / Optimizing infrared to near infrared upconversion quantum yield of β-NaYF4:Er3+ in fluoropolymer matrix for photovoltaic devices. In: Journal of Applied Physics. 2013 ; Vol. 114, No. 1.
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abstract = "The present study reports for the first time the optimization of the infrared (1523 nm) to near-infrared (980 nm) upconversion quantum yield (UC-QY) of hexagonal trivalent erbium doped sodium yttrium fluoride (β-NaYF 4:Er3+) in a perfluorocyclobutane (PFCB) host matrix under monochromatic excitation. Maximum internal and external UC-QYs of 8.4{\%} ± 0.8{\%} and 6.5{\%} ± 0.7{\%}, respectively, have been achieved for 1523 nm excitation of 970 ± 43 Wm-2 for an optimum Er3+ concentration of 25 mol{\%} and a phosphor concentration of 84.9 w/w{\%} in the matrix. These results correspond to normalized internal and external efficiencies of 0.86 ± 0.12 cm2 W-1 and 0.67 ± 0.10 cm2 W-1, respectively. These are the highest values ever reported for β-NaYF4:Er3+ under monochromatic excitation. The special characteristics of both the UC phosphor β-NaYF4:Er3+ and the PFCB matrix give rise to this outstanding property. Detailed power and time dependent luminescence measurements reveal energy transfer upconversion as the dominant UC mechanism.",
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Ivaturi, A, MacDougall, SKW, Martín-Rodríguez, R, Quintanilla, M, Marques-Hueso, J, Krämer, KW, Meijerink, A & Richards, BS 2013, 'Optimizing infrared to near infrared upconversion quantum yield of β-NaYF4:Er3+ in fluoropolymer matrix for photovoltaic devices', Journal of Applied Physics, vol. 114, no. 1, 013505. https://doi.org/10.1063/1.4812578

Optimizing infrared to near infrared upconversion quantum yield of β-NaYF4:Er3+ in fluoropolymer matrix for photovoltaic devices. / Ivaturi, Aruna; MacDougall, Sean K. W.; Martín-Rodríguez, Rosa; Quintanilla, Marta; Marques-Hueso, Jose; Krämer, Karl W.; Meijerink, Andries; Richards, Bryce S.

In: Journal of Applied Physics, Vol. 114, No. 1, 013505, 07.07.2013.

Research output: Contribution to journalArticle

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T1 - Optimizing infrared to near infrared upconversion quantum yield of β-NaYF4:Er3+ in fluoropolymer matrix for photovoltaic devices

AU - Ivaturi, Aruna

AU - MacDougall, Sean K. W.

AU - Martín-Rodríguez, Rosa

AU - Quintanilla, Marta

AU - Marques-Hueso, Jose

AU - Krämer, Karl W.

AU - Meijerink, Andries

AU - Richards, Bryce S.

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N2 - The present study reports for the first time the optimization of the infrared (1523 nm) to near-infrared (980 nm) upconversion quantum yield (UC-QY) of hexagonal trivalent erbium doped sodium yttrium fluoride (β-NaYF 4:Er3+) in a perfluorocyclobutane (PFCB) host matrix under monochromatic excitation. Maximum internal and external UC-QYs of 8.4% ± 0.8% and 6.5% ± 0.7%, respectively, have been achieved for 1523 nm excitation of 970 ± 43 Wm-2 for an optimum Er3+ concentration of 25 mol% and a phosphor concentration of 84.9 w/w% in the matrix. These results correspond to normalized internal and external efficiencies of 0.86 ± 0.12 cm2 W-1 and 0.67 ± 0.10 cm2 W-1, respectively. These are the highest values ever reported for β-NaYF4:Er3+ under monochromatic excitation. The special characteristics of both the UC phosphor β-NaYF4:Er3+ and the PFCB matrix give rise to this outstanding property. Detailed power and time dependent luminescence measurements reveal energy transfer upconversion as the dominant UC mechanism.

AB - The present study reports for the first time the optimization of the infrared (1523 nm) to near-infrared (980 nm) upconversion quantum yield (UC-QY) of hexagonal trivalent erbium doped sodium yttrium fluoride (β-NaYF 4:Er3+) in a perfluorocyclobutane (PFCB) host matrix under monochromatic excitation. Maximum internal and external UC-QYs of 8.4% ± 0.8% and 6.5% ± 0.7%, respectively, have been achieved for 1523 nm excitation of 970 ± 43 Wm-2 for an optimum Er3+ concentration of 25 mol% and a phosphor concentration of 84.9 w/w% in the matrix. These results correspond to normalized internal and external efficiencies of 0.86 ± 0.12 cm2 W-1 and 0.67 ± 0.10 cm2 W-1, respectively. These are the highest values ever reported for β-NaYF4:Er3+ under monochromatic excitation. The special characteristics of both the UC phosphor β-NaYF4:Er3+ and the PFCB matrix give rise to this outstanding property. Detailed power and time dependent luminescence measurements reveal energy transfer upconversion as the dominant UC mechanism.

KW - doping

KW - phosphors

KW - photons

KW - absorption spectra

KW - powders

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