On the role(s) of additives in bioinspired silicification

S V Patwardhan, S J Clarson, C C Perry

Research output: Contribution to journalArticle

203 Citations (Scopus)

Abstract

Biological organisms are able to direct the formation of patterned and hierarchical biomineral structures. Extractable organic materials have been found entrapped in diatom, sponge and plant biosilica, some of which have been isolated by selective chemical dissolution methods and their composition and structure studied. Information gained from the bioextracts has inspired materials chemists to design biomimetic analogues and develop bioinspired synthetic schemes for silica formation. The results obtained from bioinspired silicification investigations are hypothesised to arise from specific modes of action of the organic additives, which are described in this review. Specifically, additives in bioinspired silicification act either as catalysts, aggregation promoting agents or structure-directing agents or more typically, exhibit a combination of these behaviours.

LanguageEnglish
Pages1113-1121
Number of pages9
JournalChemical Communications (London)
Issue number9
DOIs
Publication statusPublished - 2005

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Biomimetics
Silicon Dioxide
Dissolution
Agglomeration
Catalysts
Chemical analysis

Keywords

  • si-29 nmr shifts
  • silica structures
  • mesoporous silica
  • colloidal silica
  • diatom frustule
  • organic matrix
  • amino acids
  • complexes
  • biosilification

Cite this

Patwardhan, S V ; Clarson, S J ; Perry, C C . / On the role(s) of additives in bioinspired silicification. In: Chemical Communications (London). 2005 ; No. 9. pp. 1113-1121.
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On the role(s) of additives in bioinspired silicification. / Patwardhan, S V ; Clarson, S J ; Perry, C C .

In: Chemical Communications (London), No. 9, 2005, p. 1113-1121.

Research output: Contribution to journalArticle

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