Abstract
Olefin cross metathesis has been employed for the first time for the post-polymerization chemical modification of porous polymers. High quality microspheres of poly(divinylbenzene) were synthesized by the precipitation polymerization of divi-nylbenzene-55 in porogenic solvents, and the olefin cross metathesis reactions of the pendent (polymer-bound) vinyl groups not consumed by polymerization were performed with diverse coupling partners in dichloromethane using the Grubbs 2 catalyst, leading to microspheres decorated with a wide range of functional groups.
| Original language | English |
|---|---|
| Pages (from-to) | 2481-2485 |
| Number of pages | 5 |
| Journal | Organic Letters |
| Volume | 22 |
| Issue number | 6 |
| Early online date | 4 Mar 2020 |
| DOIs | |
| Publication status | Published - 20 Mar 2020 |
Keywords
- olefin cross metathesis
- polymers
- porous resins
Fingerprint
Dive into the research topics of 'Olefin cross metathesis as a versatile method for the facile functionalization of porous polymers'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver