Olefin cross metathesis as a versatile method for the facile functionalization of porous polymers

Amaia  Altuna-Ruiz de Aguino; Peter A. G. Cormack; Joëlle Prunet

doi:10.1021/acs.orglett.0c00726

Olefin cross metathesis as a versatile method for the facile functionalization of porous polymers

Amaia Altuna-Ruiz de Aguino, Peter A. G. Cormack, Joëlle Prunet

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

9 Downloads (Pure)

Abstract

Olefin cross metathesis has been employed for the first time for the post-polymerization chemical modification of porous polymers. High quality microspheres of poly(divinylbenzene) were synthesized by the precipitation polymerization of divi-nylbenzene-55 in porogenic solvents, and the olefin cross metathesis reactions of the pendent (polymer-bound) vinyl groups not consumed by polymerization were performed with diverse coupling partners in dichloromethane using the Grubbs 2 catalyst, leading to microspheres decorated with a wide range of functional groups.

Original language	English
Pages (from-to)	2481-2485
Number of pages	5
Journal	Organic Letters
Volume	22
Issue number	6
Early online date	4 Mar 2020
DOIs	https://doi.org/10.1021/acs.orglett.0c00726
Publication status	Published - 20 Mar 2020

Keywords

olefin cross metathesis
polymers
porous resins

Access to Document

10.1021/acs.orglett.0c00726

Aguino-etal-OL-2020-Olefin-cross-metathesis-as-a-versatile-method-for-the-facile-functionalizationAccepted author manuscript, 506 KB

Cite this

@article{79db0e2495fa47b7b9ceb4c11f9a0272,

title = "Olefin cross metathesis as a versatile method for the facile functionalization of porous polymers",

abstract = "Olefin cross metathesis has been employed for the first time for the post-polymerization chemical modification of porous polymers. High quality microspheres of poly(divinylbenzene) were synthesized by the precipitation polymerization of divi-nylbenzene-55 in porogenic solvents, and the olefin cross metathesis reactions of the pendent (polymer-bound) vinyl groups not consumed by polymerization were performed with diverse coupling partners in dichloromethane using the Grubbs 2 catalyst, leading to microspheres decorated with a wide range of functional groups.",

keywords = "olefin cross metathesis, polymers, porous resins",

author = "{Altuna-Ruiz de Aguino}, Amaia and Cormack, {Peter A. G.} and Jo{\"e}lle Prunet",

year = "2020",

month = mar,

day = "20",

doi = "10.1021/acs.orglett.0c00726",

language = "English",

volume = "22",

pages = "2481--2485",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Olefin cross metathesis as a versatile method for the facile functionalization of porous polymers

AU - Altuna-Ruiz de Aguino, Amaia

AU - Cormack, Peter A. G.

AU - Prunet, Joëlle

PY - 2020/3/20

Y1 - 2020/3/20

N2 - Olefin cross metathesis has been employed for the first time for the post-polymerization chemical modification of porous polymers. High quality microspheres of poly(divinylbenzene) were synthesized by the precipitation polymerization of divi-nylbenzene-55 in porogenic solvents, and the olefin cross metathesis reactions of the pendent (polymer-bound) vinyl groups not consumed by polymerization were performed with diverse coupling partners in dichloromethane using the Grubbs 2 catalyst, leading to microspheres decorated with a wide range of functional groups.

AB - Olefin cross metathesis has been employed for the first time for the post-polymerization chemical modification of porous polymers. High quality microspheres of poly(divinylbenzene) were synthesized by the precipitation polymerization of divi-nylbenzene-55 in porogenic solvents, and the olefin cross metathesis reactions of the pendent (polymer-bound) vinyl groups not consumed by polymerization were performed with diverse coupling partners in dichloromethane using the Grubbs 2 catalyst, leading to microspheres decorated with a wide range of functional groups.

KW - olefin cross metathesis

KW - polymers

KW - porous resins

UR - https://pubs.acs.org/journal/orlef7

U2 - 10.1021/acs.orglett.0c00726

DO - 10.1021/acs.orglett.0c00726

M3 - Article

SN - 1523-7060

VL - 22

SP - 2481

EP - 2485

JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Olefin cross metathesis as a versatile method for the facile functionalization of porous polymers

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this