Abstract
| Language | Undefined/Unknown |
|---|---|
| Pages | 8553-8556 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 34 |
| Issue number | 52 |
| DOIs | |
| Publication status | Published - 1993 |
Keywords
- cyclizations
- vinyl sulfones
- perhydroazulenes
- trans-hydrindanes
Cite this
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Novel cyclizations involving vinyl sulfones: stereoselective construction of perhydroazulenes and trans-hydrindanes. / Jones, D. Neville; Maybury, Mark W. J.; Swallow, Steven; Tomkinson, Nicholas C. O.
In: Tetrahedron Letters, Vol. 34, No. 52, 1993, p. 8553-8556.Research output: Contribution to journal › Article
TY - JOUR
T1 - Novel cyclizations involving vinyl sulfones: stereoselective construction of perhydroazulenes and trans-hydrindanes
AU - Jones, D. Neville
AU - Maybury, Mark W. J.
AU - Swallow, Steven
AU - Tomkinson, Nicholas C. O.
PY - 1993
Y1 - 1993
N2 - Anionic species formed by treatment of vinyl sulfones with hydridoaluminates were trapped intramolecularly by esters to provide six- and seven-membered cyclic ketosulfones, e.g. I (R = Me, H, Ar = p-tolyl) and II, exemplified by the stereoselective construction of trans-hydrindanes and of perhydroazulenes. This led to formal syntheses of confertin (III) and damsinic acid.
AB - Anionic species formed by treatment of vinyl sulfones with hydridoaluminates were trapped intramolecularly by esters to provide six- and seven-membered cyclic ketosulfones, e.g. I (R = Me, H, Ar = p-tolyl) and II, exemplified by the stereoselective construction of trans-hydrindanes and of perhydroazulenes. This led to formal syntheses of confertin (III) and damsinic acid.
KW - cyclizations
KW - vinyl sulfones
KW - perhydroazulenes
KW - trans-hydrindanes
U2 - 10.1016/S0040-4039(00)61383-7
DO - 10.1016/S0040-4039(00)61383-7
M3 - Article
VL - 34
SP - 8553
EP - 8556
JO - Tetrahedron Letters
T2 - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 52
ER -