Nitric oxide species as oxidising agents and adducts for soft scorpionates

R. Rajasekharan-Nair, L. Darby, J. Reglinski, M.D. Spicer, A.R. Kennedy

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Bis-(κ-H,S,S-dihydrobis-(methimazolyl)borato) ruthenium(II), [Ru(Bm)], has been prepared and tested as a nitric oxide scavenger using NO, NOBF and NOBr. The products isolated show that, NO and NO are good one electron oxidising agents towards the ruthenium complexes but NO is not coordinated to the metal. The oxidised species, [Ru(Bm)]BF has been isolated and characterised. Reaction of "Ru(NO)Cl" with NaBm results in the removal of the borohydride from the ligand and formation of [Ru(mtH)(mt)(NO)Cl].
LanguageEnglish
Pages11-13
Number of pages3
JournalInorganic Chemistry Communications
Volume41
DOIs
Publication statusPublished - 1 Mar 2014

Fingerprint

Ruthenium
Nitric oxide
nitric oxide
Oxidants
ruthenium
adducts
Nitric Oxide
Borohydrides
borohydrides
Metals
Ligands
ligands
Electrons
products
metals
electrons
benfluron N-oxide

Keywords

  • nitric oxide
  • oxidising agent
  • soft scorpionates
  • π-acids

Cite this

Rajasekharan-Nair, R. ; Darby, L. ; Reglinski, J. ; Spicer, M.D. ; Kennedy, A.R. / Nitric oxide species as oxidising agents and adducts for soft scorpionates. In: Inorganic Chemistry Communications. 2014 ; Vol. 41. pp. 11-13.
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Nitric oxide species as oxidising agents and adducts for soft scorpionates. / Rajasekharan-Nair, R.; Darby, L.; Reglinski, J.; Spicer, M.D.; Kennedy, A.R.

In: Inorganic Chemistry Communications, Vol. 41, 01.03.2014, p. 11-13.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Nitric oxide species as oxidising agents and adducts for soft scorpionates

AU - Rajasekharan-Nair, R.

AU - Darby, L.

AU - Reglinski, J.

AU - Spicer, M.D.

AU - Kennedy, A.R.

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AB - Bis-(κ-H,S,S-dihydrobis-(methimazolyl)borato) ruthenium(II), [Ru(Bm)], has been prepared and tested as a nitric oxide scavenger using NO, NOBF and NOBr. The products isolated show that, NO and NO are good one electron oxidising agents towards the ruthenium complexes but NO is not coordinated to the metal. The oxidised species, [Ru(Bm)]BF has been isolated and characterised. Reaction of "Ru(NO)Cl" with NaBm results in the removal of the borohydride from the ligand and formation of [Ru(mtH)(mt)(NO)Cl].

KW - nitric oxide

KW - oxidising agent

KW - soft scorpionates

KW - π-acids

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