Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te)

Nikolaos Levesanos; Stuart D. Robertson; Dimitrios Maganas; Catherine P. Raptopoulou; Aris Terzis; Panayotis Kyritsis; Tristram Chivers

doi:10.1021/ic800272v

Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te)

Nikolaos Levesanos, Stuart D. Robertson, Dimitrios Maganas, Catherine P. Raptopoulou, Aris Terzis, Panayotis Kyritsis, Tristram Chivers

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

Original language	English
Pages (from-to)	2949-2951
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	8
Early online date	15 Mar 2008
DOIs	https://doi.org/10.1021/ic800272v
Publication status	Published - 21 Apr 2008

Keywords

single-crystal characterization
nickel(II) complexes
discrete mononuclear
fenise hydrogenases
chemistry
ligands
ditelluroimidodiphosphinate
dehydrogenase
catalysis
M=NI

Access to Document

10.1021/ic800272v

Cite this

@article{d558b54ef63645b3bccf339ecdaaef2c,

title = "Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te)",

abstract = "The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).",

keywords = "single-crystal characterization, nickel(II) complexes, discrete mononuclear, fenise hydrogenases, chemistry, ligands, ditelluroimidodiphosphinate, dehydrogenase, catalysis, M=NI",

author = "Nikolaos Levesanos and Robertson, {Stuart D.} and Dimitrios Maganas and Raptopoulou, {Catherine P.} and Aris Terzis and Panayotis Kyritsis and Tristram Chivers",

year = "2008",

month = apr,

day = "21",

doi = "10.1021/ic800272v",

language = "English",

volume = "47",

pages = "2949--2951",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Ni[((EPPr2)-Pr-i)(2)N](2) complexes

T2 - stereolsomers (E = se) and square-planar coordination (E = te)

AU - Levesanos, Nikolaos

AU - Robertson, Stuart D.

AU - Maganas, Dimitrios

AU - Raptopoulou, Catherine P.

AU - Terzis, Aris

AU - Kyritsis, Panayotis

AU - Chivers, Tristram

PY - 2008/4/21

Y1 - 2008/4/21

N2 - The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

AB - The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

KW - single-crystal characterization

KW - nickel(II) complexes

KW - discrete mononuclear

KW - fenise hydrogenases

KW - chemistry

KW - ligands

KW - ditelluroimidodiphosphinate

KW - dehydrogenase

KW - catalysis

KW - M=NI

U2 - 10.1021/ic800272v

DO - 10.1021/ic800272v

M3 - Article

SN - 0020-1669

VL - 47

SP - 2949

EP - 2951

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -

Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te)

Abstract

Keywords

Access to Document

Fingerprint

Cite this