Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te)

Nikolaos Levesanos, Stuart D. Robertson, Dimitrios Maganas, Catherine P. Raptopoulou, Aris Terzis, Panayotis Kyritsis, Tristram Chivers

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Abstract

The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

Original languageEnglish
Pages (from-to)2949-2951
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number8
Early online date15 Mar 2008
DOIs
Publication statusPublished - 21 Apr 2008

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Keywords

  • single-crystal characterization
  • nickel(II) complexes
  • discrete mononuclear
  • fenise hydrogenases
  • chemistry
  • ligands
  • ditelluroimidodiphosphinate
  • dehydrogenase
  • catalysis
  • M=NI

Cite this

Levesanos, N., Robertson, S. D., Maganas, D., Raptopoulou, C. P., Terzis, A., Kyritsis, P., & Chivers, T. (2008). Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te). Inorganic Chemistry, 47(8), 2949-2951. https://doi.org/10.1021/ic800272v