Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te)

Nikolaos Levesanos, Stuart D. Robertson, Dimitrios Maganas, Catherine P. Raptopoulou, Aris Terzis, Panayotis Kyritsis, Tristram Chivers

Research output: Contribution to journalArticle

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Abstract

The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

LanguageEnglish
Pages2949-2951
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number8
Early online date15 Mar 2008
DOIs
Publication statusPublished - 21 Apr 2008

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Stereoisomerism
analogs
phenyllithium
Green Or

Keywords

  • single-crystal characterization
  • nickel(II) complexes
  • discrete mononuclear
  • fenise hydrogenases
  • chemistry
  • ligands
  • ditelluroimidodiphosphinate
  • dehydrogenase
  • catalysis
  • M=NI

Cite this

Levesanos, N., Robertson, S. D., Maganas, D., Raptopoulou, C. P., Terzis, A., Kyritsis, P., & Chivers, T. (2008). Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te). Inorganic Chemistry, 47(8), 2949-2951. https://doi.org/10.1021/ic800272v
Levesanos, Nikolaos ; Robertson, Stuart D. ; Maganas, Dimitrios ; Raptopoulou, Catherine P. ; Terzis, Aris ; Kyritsis, Panayotis ; Chivers, Tristram. / Ni[((EPPr2)-Pr-i)(2)N](2) complexes : stereolsomers (E = se) and square-planar coordination (E = te). In: Inorganic Chemistry. 2008 ; Vol. 47, No. 8. pp. 2949-2951.
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abstract = "The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).",
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Levesanos, N, Robertson, SD, Maganas, D, Raptopoulou, CP, Terzis, A, Kyritsis, P & Chivers, T 2008, 'Ni[((EPPr2)-Pr-i)(2)N](2) complexes: stereolsomers (E = se) and square-planar coordination (E = te)' Inorganic Chemistry, vol. 47, no. 8, pp. 2949-2951. https://doi.org/10.1021/ic800272v

Ni[((EPPr2)-Pr-i)(2)N](2) complexes : stereolsomers (E = se) and square-planar coordination (E = te). / Levesanos, Nikolaos; Robertson, Stuart D.; Maganas, Dimitrios; Raptopoulou, Catherine P.; Terzis, Aris; Kyritsis, Panayotis; Chivers, Tristram.

In: Inorganic Chemistry, Vol. 47, No. 8, 21.04.2008, p. 2949-2951.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Ni[((EPPr2)-Pr-i)(2)N](2) complexes

T2 - Inorganic Chemistry

AU - Levesanos, Nikolaos

AU - Robertson, Stuart D.

AU - Maganas, Dimitrios

AU - Raptopoulou, Catherine P.

AU - Terzis, Aris

AU - Kyritsis, Panayotis

AU - Chivers, Tristram

PY - 2008/4/21

Y1 - 2008/4/21

N2 - The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

AB - The reaction of ((Pr2PE)-Pr-i)(2)NM center dot TMEDA (M = Li, E = Se; M = Na, E = Te) with NiBr2 center dot DME in THF affords Ni[((SePPr2)-Pr-i)(2)N](2) as either square-planar (green) or tetrahedral (red) stereoisomers, depending on the recrystallization solvent; the Te analogue is obtained as the square-planar complex Ni[(TeP(i)pr(2))(2)N](2).

KW - single-crystal characterization

KW - nickel(II) complexes

KW - discrete mononuclear

KW - fenise hydrogenases

KW - chemistry

KW - ligands

KW - ditelluroimidodiphosphinate

KW - dehydrogenase

KW - catalysis

KW - M=NI

U2 - 10.1021/ic800272v

DO - 10.1021/ic800272v

M3 - Article

VL - 47

SP - 2949

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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