Neutral organic super electron donors made catalytic

Simon Rohrbach, Rushabh S. Shah, Tell Tuttle, John A. Murphy

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)
1 Downloads (Pure)

Abstract

Neutral organic super electron donors (SEDs) display impressive reducing power but, until now, it has not been possible to use them catalytically in radical chain reactions. This is because, following electron transfer, these donors form persistent radical cations that trap substrate-derived radicals. This paper unlocks a conceptually new approach to super electron donors that overcomes this issue, leading to the first catalytic neutral organic super electron donor.
Original languageEnglish
Pages (from-to)11454-11458
Number of pages5
JournalAngewandte Chemie International Edition
Volume58
Issue number33
Early online date20 Jun 2019
DOIs
Publication statusPublished - 12 Aug 2019

Keywords

  • catalysis
  • upconversion
  • organic electron donor
  • reduction
  • single electron transfer

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