Abstract
We define a continuum energy functional that effectively interpolates between the mean-field Maier-Saupe energy and the continuum Landau-de Gennes energy functional and can describe both spatially homogeneous and inhomogeneous systems. In the mean-field approach the main macroscopic variable, the Q-tensor order parameter, is defined in terms of the second moment of a probability distribution function. This definition imposes certain constraints on the eigenvalues of the Q-tensor order parameter, which may be interpreted as physical constraints. We define a thermotropic bulk potential which blows up whenever the eigenvalues of the Q-tensor order parameter approach physically unrealistic values. As a consequence, the minimizers of this continuum energy functional have physically realistic order parameters in all temperature regimes. We study the asymptotics of this bulk potential and show that this model also predicts a first-order nematic-isotropic phase transition, whilst respecting the physical constraints. In contrast, in the Landau-de Gennes framework the Q-tensor order parameter is often defined independently of the probability distribution function, and the theory makes physically unrealistic predictions about the equilibrium order parameters in the low-temperature regime
Original language | Undefined/Unknown |
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Pages (from-to) | 1-11 |
Number of pages | 12 |
Journal | Molecular Crystals and Liquid Crystals |
Volume | 525 |
Issue number | 1 |
DOIs | |
Publication status | Published - 13 Jul 2010 |
Keywords
- eigenvalue constraints
- elastic constants
- Landau-de Gennes theory
- Maier-Saupe
- nematic liquid crystals