The use of an air and moisture stable, commercially available (N-heterocyclic carbene)-Pd complex as precatalyst allows for the unprecedented Buchwald-Hartwig polyamination of aryl chlorides with primary amines. Different approaches for the end-capping of the polymers have also been evaluated.
|Number of pages||6|
|Journal||Journal of Polymer Science, Part A: Polymer Chemistry|
|Publication status||Published - 15 Oct 2012|
- Buchwald-Hartwig coupling
- N-heterocyclic carbene
- semiconducting polymer