N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide

Rodolfo Moreno-Fuquen; Alexis Azcárate; Alan R Kennedy

doi:10.1107/S160053681400912X

N-(2-Nitrophenyl)thiophene-2-carboxamide

Rodolfo Moreno-Fuquen, Alexis Azcárate, Alan R Kennedy

Pure And Applied Chemistry

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

The title compound, C₁₁H₈N₂O₃S, shows two molecules per asymmetric unit, with the dihedral angles between the benzene and thiophene rings of 13.53 (6) and 8.50 (5)°
being a notable difference between them. An intramolecular N-HO hydrogen-bond in each molecule generates an S(6) ring motif. The crystal packing shows no classical hydrogen bonds with the molecules being packed to form weak C-HO and C-HS interactions leading to R₂²(9) and R₄⁴(25) rings which are edge-shared, giving layers parallel to (010).

Original language	English
Article number	o613
Number of pages	9
Journal	Acta Crystallographica Section E: Structure Reports
Volume	70
Issue number	5
DOIs	https://doi.org/10.1107/S160053681400912X
Publication status	Published - 1 May 2014

Keywords

benzene
thiophene
molecules
crystal structure

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10.1107/S160053681400912X

x-ray diffractometer
Kennedy, A.
Pure And Applied Chemistry
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@article{11af401a90e144a5a8ef2b59d53e203c,

title = "N-(2-Nitrophenyl)thiophene-2-carboxamide",

abstract = "The title compound, C11H8N2O3S, shows two molecules per asymmetric unit, with the dihedral angles between the benzene and thiophene rings of 13.53 (6) and 8.50 (5)° being a notable difference between them. An intramolecular N-HO hydrogen-bond in each molecule generates an S(6) ring motif. The crystal packing shows no classical hydrogen bonds with the molecules being packed to form weak C-HO and C-HS interactions leading to R22(9) and R44(25) rings which are edge-shared, giving layers parallel to (010).",

keywords = "benzene , thiophene, molecules, crystal structure",

author = "Rodolfo Moreno-Fuquen and Alexis Azc{\'a}rate and Kennedy, \{Alan R\}",

year = "2014",

month = may,

day = "1",

doi = "10.1107/S160053681400912X",

language = "English",

volume = "70",

journal = "Acta Crystallographica Section E: Structure Reports",

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TY - JOUR

T1 - N-(2-Nitrophenyl)thiophene-2-carboxamide

AU - Moreno-Fuquen, Rodolfo

AU - Azcárate, Alexis

AU - Kennedy, Alan R

PY - 2014/5/1

Y1 - 2014/5/1

N2 - The title compound, C11H8N2O3S, shows two molecules per asymmetric unit, with the dihedral angles between the benzene and thiophene rings of 13.53 (6) and 8.50 (5)° being a notable difference between them. An intramolecular N-HO hydrogen-bond in each molecule generates an S(6) ring motif. The crystal packing shows no classical hydrogen bonds with the molecules being packed to form weak C-HO and C-HS interactions leading to R22(9) and R44(25) rings which are edge-shared, giving layers parallel to (010).

AB - The title compound, C11H8N2O3S, shows two molecules per asymmetric unit, with the dihedral angles between the benzene and thiophene rings of 13.53 (6) and 8.50 (5)° being a notable difference between them. An intramolecular N-HO hydrogen-bond in each molecule generates an S(6) ring motif. The crystal packing shows no classical hydrogen bonds with the molecules being packed to form weak C-HO and C-HS interactions leading to R22(9) and R44(25) rings which are edge-shared, giving layers parallel to (010).

KW - benzene

KW - thiophene

KW - molecules

KW - crystal structure

U2 - 10.1107/S160053681400912X

DO - 10.1107/S160053681400912X

M3 - Article

C2 - 24860404

SN - 1600-5368

VL - 70

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

IS - 5

M1 - o613

ER -

N-(2-Nitro­phen­yl)thio­phene-2-carbox­amide

Abstract

Keywords

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N-(2-Nitrophenyl)thiophene-2-carboxamide