Multiscale modeling of island nucleation and growth during cu(100) homoepitaxy

M. Basham, F. Montalenti, P.A. Mulheran

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)


The long-time scale dynamics of small Cu/Cu(100) islands are studied. Atomistic simulations using embedded atom method (EAM) potentials and the dimer method saddle point searches provide pathways and their temperature-dependent rates to lattice-based kinetic Monte Carlo (KMC) simulations. The KMC utilizes translational symmetry to identify previously visited sites and re-use the atomistic rates. As a result very long time scales are accessible to the simulation which reveals the dissociation as well as the diffusion mechanisms of the small islands in an unbiased manner. Our results for island diffusion reproduce well the activation energies calculated in previous work, and provide in addition the associated frequency prefactors. The island dissociation pathways are rationalized in terms of previously anticipated mechanisms. We also utilize our results in mean field rate equations to predict "kinetic phase diagrams" for the critical island size as a function of temperature and vapor deposition rate during Cu(100) homoepitaxy. We predict that the higher critical island sizes (i>2) should be observable at higher temperatures (above ~500 K) at experimentally accessible deposition rates.
Original languageEnglish
Pages (from-to)045422
JournalPhysical Review B
Issue number4
Publication statusPublished - 2006


  • submonolayer epitaxial-growth
  • metal 100 surfaces
  • thin-film growth
  • cluster diffusion
  • size distributions
  • capture zones
  • dynamics
  • kinetics
  • dissociation
  • simulation
  • copper
  • nucleation
  • discontinuous metallic thin films
  • metallic epitaxial layers
  • vapour phase epitaxial growth
  • Monte Carlo methods
  • diffusion
  • phase diagrams


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