Multidentate ligands for the synthesis of multi-metallic complexes. 2. Formation of a planar Cu4OH motif

Abdullahi Mustapha; J. Reglinski; Alan R. Kennedy; D.R. Armstrong; Jorg Sassmannshausen; Mark Murrie

doi:10.1021/ic100594n

Multidentate ligands for the synthesis of multi-metallic complexes. 2. Formation of a planar Cu4OH motif

Abdullahi Mustapha, J. Reglinski, Alan R. Kennedy, D.R. Armstrong, Jorg Sassmannshausen, Mark Murrie

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reaction of the multidentate Schiff base species TrenSal, TrenBrSal and TEtSal with copper acetate is reported. The heptadentate ligands generate a tetrametallic L2Cu4OH motif that contains an internalised hydroxide anion. In contrast the hexadentate TEtSal ligand is found to form an open trimetallic motif. The importance of L2Cu4OH to the family of copper ccmplexes with an endohedral hydroxide anion is discussed. [(TrenBrSal)2Cu4OH] [OAc] is analysed by temperature dependent magnetic measurements.

Original language	English
Pages (from-to)	5350-5352
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	12
Early online date	18 May 2010
DOIs	https://doi.org/10.1021/ic100594n
Publication status	Published - 2010

Keywords

multidentate ligands
multi-metallic complexes
inorganic chemistry

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10.1021/ic100594n

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title = "Multidentate ligands for the synthesis of multi-metallic complexes. 2. Formation of a planar Cu4OH motif",

abstract = "The reaction of the multidentate Schiff base species TrenSal, TrenBrSal and TEtSal with copper acetate is reported. The heptadentate ligands generate a tetrametallic L2Cu4OH motif that contains an internalised hydroxide anion. In contrast the hexadentate TEtSal ligand is found to form an open trimetallic motif. The importance of L2Cu4OH to the family of copper ccmplexes with an endohedral hydroxide anion is discussed. [(TrenBrSal)2Cu4OH] [OAc] is analysed by temperature dependent magnetic measurements.",

keywords = "multidentate ligands, multi-metallic complexes, inorganic chemistry",

author = "Abdullahi Mustapha and J. Reglinski and Kennedy, {Alan R.} and D.R. Armstrong and Jorg Sassmannshausen and Mark Murrie",

year = "2010",

doi = "10.1021/ic100594n",

language = "English",

volume = "49",

pages = "5350--5352",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Multidentate ligands for the synthesis of multi-metallic complexes. 2. Formation of a planar Cu4OH motif

AU - Mustapha, Abdullahi

AU - Reglinski, J.

AU - Kennedy, Alan R.

AU - Armstrong, D.R.

AU - Sassmannshausen, Jorg

AU - Murrie, Mark

PY - 2010

Y1 - 2010

N2 - The reaction of the multidentate Schiff base species TrenSal, TrenBrSal and TEtSal with copper acetate is reported. The heptadentate ligands generate a tetrametallic L2Cu4OH motif that contains an internalised hydroxide anion. In contrast the hexadentate TEtSal ligand is found to form an open trimetallic motif. The importance of L2Cu4OH to the family of copper ccmplexes with an endohedral hydroxide anion is discussed. [(TrenBrSal)2Cu4OH] [OAc] is analysed by temperature dependent magnetic measurements.

AB - The reaction of the multidentate Schiff base species TrenSal, TrenBrSal and TEtSal with copper acetate is reported. The heptadentate ligands generate a tetrametallic L2Cu4OH motif that contains an internalised hydroxide anion. In contrast the hexadentate TEtSal ligand is found to form an open trimetallic motif. The importance of L2Cu4OH to the family of copper ccmplexes with an endohedral hydroxide anion is discussed. [(TrenBrSal)2Cu4OH] [OAc] is analysed by temperature dependent magnetic measurements.

KW - multidentate ligands

KW - multi-metallic complexes

KW - inorganic chemistry

UR - http://www.scopus.com/inward/record.url?scp=77953608445&partnerID=8YFLogxK

U2 - 10.1021/ic100594n

DO - 10.1021/ic100594n

M3 - Article

SN - 0020-1669

VL - 49

SP - 5350

EP - 5352

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Multidentate ligands for the synthesis of multi-metallic complexes. 2. Formation of a planar Cu4OH motif

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Multidentate ligands for the synthesis of multi-metallic complexes. 2. Formation of a planar Cu4OH motif

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