[Mo(TmMe)(O)2Cl]: an alternative functional model of sulfite oxidase

Mark Spicer; John Reglinski; Dawn Wallace; Lorraine Gibson

doi:10.1021/ic700468m

[Mo(TmMe)(O)2Cl]: an alternative functional model of sulfite oxidase

Mark Spicer, John Reglinski, Dawn Wallace, Lorraine Gibson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The hydrotris(methimazolyl)borate anion (TmMe) has been used to synthesize an alternative functional model ([Mo(TmMe)(O)2Cl]) of the metalloenzyme sulfite oxidase. It has been shown that the complex undergoes oxygen atom transfer chemistry and that it performs the primary function of the enzyme, sulfite oxidation. A method using ion chromatography has been developed to definitively prove that sulfite is oxidized to sulfate.

Original language	English
Pages (from-to)	3804 - 3806
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
DOIs	https://doi.org/10.1021/ic700468m
Publication status	Published - 2007

Keywords

sulfite oxidase
inorganic chemistry

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10.1021/ic700468m

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title = "[Mo(TmMe)(O)2Cl]: an alternative functional model of sulfite oxidase",

abstract = "The hydrotris(methimazolyl)borate anion (TmMe) has been used to synthesize an alternative functional model ([Mo(TmMe)(O)2Cl]) of the metalloenzyme sulfite oxidase. It has been shown that the complex undergoes oxygen atom transfer chemistry and that it performs the primary function of the enzyme, sulfite oxidation. A method using ion chromatography has been developed to definitively prove that sulfite is oxidized to sulfate.",

keywords = "sulfite oxidase , inorganic chemistry",

author = "Mark Spicer and John Reglinski and Dawn Wallace and Lorraine Gibson",

year = "2007",

doi = "10.1021/ic700468m",

language = "English",

volume = "46",

pages = "3804 -- 3806",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - [Mo(TmMe)(O)2Cl]: an alternative functional model of sulfite oxidase

AU - Spicer, Mark

AU - Reglinski, John

AU - Wallace, Dawn

AU - Gibson, Lorraine

PY - 2007

Y1 - 2007

N2 - The hydrotris(methimazolyl)borate anion (TmMe) has been used to synthesize an alternative functional model ([Mo(TmMe)(O)2Cl]) of the metalloenzyme sulfite oxidase. It has been shown that the complex undergoes oxygen atom transfer chemistry and that it performs the primary function of the enzyme, sulfite oxidation. A method using ion chromatography has been developed to definitively prove that sulfite is oxidized to sulfate.

AB - The hydrotris(methimazolyl)borate anion (TmMe) has been used to synthesize an alternative functional model ([Mo(TmMe)(O)2Cl]) of the metalloenzyme sulfite oxidase. It has been shown that the complex undergoes oxygen atom transfer chemistry and that it performs the primary function of the enzyme, sulfite oxidation. A method using ion chromatography has been developed to definitively prove that sulfite is oxidized to sulfate.

KW - sulfite oxidase

KW - inorganic chemistry

U2 - 10.1021/ic700468m

DO - 10.1021/ic700468m

M3 - Article

VL - 46

SP - 3804

EP - 3806

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -

[Mo(TmMe)(O)2Cl]: an alternative functional model of sulfite oxidase

Abstract

Keywords

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