Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA

Ana I. Ojeda-Amador, Antonio J. Martínez-Martínez, Alan R. Kennedy, David R. Armstrong, Charles T. O'Hara

Research output: Contribution to journalArticle

4 Citations (Scopus)
102 Downloads (Pure)

Abstract

After isolating an unusual binuclear, but monosolvated NaHMDS complex [{(R,R)-TMCDA}·(NaHMDS)2] which polymerises via intermolecular electrostatic Na···MeHMDS interactions, further (R,R)-TMCDA was added to produce the discrete binuclear amide [κ2-{(R,R)-TMCDA}·(NaHMDS)21-(R,R)-TMCDA}], whose salient feature is the unique monodentate coordination of one of the chiral diamine ligands.
Original languageEnglish
Pages (from-to)324-327
Number of pages4
JournalChemical Communications
Volume53
Early online date7 Dec 2016
DOIs
Publication statusPublished - 7 Jan 2017

Keywords

  • sodium
  • amide
  • organometallic
  • chiral amine
  • X-ray crystal structures

Fingerprint Dive into the research topics of 'Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA'. Together they form a unique fingerprint.

  • Profiles

    Projects

    Datasets

    Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA

    O'Hara, C. (Creator), Martinez-Martinez, A. (Contributor), Ojeda Amador, A. I. (Contributor) & Kennedy, A. (Contributor), University of Strathclyde, 1 Sep 2016

    Dataset

    Equipment

    x-ray diffractometer

    Alan Kennedy (Manager)

    Pure And Applied Chemistry

    Facility/equipment: Equipment

  • Cite this