Projects per year
Abstract
After isolating an unusual binuclear, but monosolvated NaHMDS complex [{(R,R)-TMCDA}·(NaHMDS)2]∞ which polymerises via intermolecular electrostatic Na···MeHMDS interactions, further (R,R)-TMCDA was added to produce the discrete binuclear amide [κ2-{(R,R)-TMCDA}·(NaHMDS)2{κ1-(R,R)-TMCDA}], whose salient feature is the unique monodentate coordination of one of the chiral diamine ligands.
Original language | English |
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Pages (from-to) | 324-327 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 53 |
Early online date | 7 Dec 2016 |
DOIs | |
Publication status | Published - 7 Jan 2017 |
Keywords
- sodium
- amide
- organometallic
- chiral amine
- X-ray crystal structures
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Dive into the research topics of 'Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA'. Together they form a unique fingerprint.Profiles
Projects
- 3 Finished
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Chiral Concepts in s-Block Metal Amide Chemistry | Ojeda Amador, Ana Isabel
O'Hara, C., Mulvey, R. & Ojeda Amador, A. I.
EPSRC (Engineering and Physical Sciences Research Council)
1/10/12 → 21/11/16
Project: Research Fellowship - Internally Allocated
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Chiral Concepts in s-Block Metal Amide Chemistry
EPSRC (Engineering and Physical Sciences Research Council)
1/10/11 → 30/09/16
Project: Research Fellowship
Datasets
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Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA
O'Hara, C. (Creator), Martinez-Martinez, A. (Contributor), Ojeda Amador, A. I. (Contributor) & Kennedy, A. (Contributor), University of Strathclyde, 1 Sep 2016
DOI: 10.15129/103ad89d-550d-44ad-8aa8-62d54c47e3ac
Dataset