Molecular-salt hybrids; integration of ammonia borane into lithium halides

Irene Cascallana-Matías; Joachim Breternitz; Annabelle Baker; Hallam Davis; Edmund J. Cussen; Duncan H. Gregory

doi:10.1039/c9qi00099b

Molecular-salt hybrids; integration of ammonia borane into lithium halides

Irene Cascallana-Matías, Joachim Breternitz, Annabelle Baker, Hallam Davis, Edmund J. Cussen, Duncan H. Gregory^*

^*Corresponding author for this work

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

10 Downloads (Pure)

Abstract

New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH₃BH₃) and [LiI](NH₃BH₃)₂ are members of a generic [LiX]_m(AB)_n (X = I^-, BH₄^-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li⁺-ion conductivity more than two orders of magnitude higher than either LiBH₄ or LiI.

Original language	English
Pages (from-to)	808-812
Number of pages	5
Journal	Inorganic Chemistry Frontiers
Volume	6
Issue number	3
Early online date	18 Feb 2019
DOIs	https://doi.org/10.1039/c9qi00099b
Publication status	Published - 1 Mar 2019

Keywords

lithium alanates
borohydrides
LiBH4
electrochemical stability

Access to Document

10.1039/c9qi00099bLicence: CC BY 3.0

Cascallana-Matias-etal-ICF-2019-integration-of-ammonia-borane-into-lithium-halidesFinal published version, 839 KBLicence: CC BY 3.0

Cite this

@article{c82b4c2dbae241b986612ba5ebbbe571,

title = "Molecular-salt hybrids; integration of ammonia borane into lithium halides",

abstract = "New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.",

keywords = "lithium alanates, borohydrides, LiBH4, electrochemical stability",

author = "Irene Cascallana-Mat{\'i}as and Joachim Breternitz and Annabelle Baker and Hallam Davis and Cussen, \{Edmund J.\} and Gregory, \{Duncan H.\}",

year = "2019",

month = mar,

day = "1",

doi = "10.1039/c9qi00099b",

language = "English",

volume = "6",

pages = "808--812",

number = "3",

}

TY - JOUR

T1 - Molecular-salt hybrids; integration of ammonia borane into lithium halides

AU - Cascallana-Matías, Irene

AU - Breternitz, Joachim

AU - Baker, Annabelle

AU - Davis, Hallam

AU - Cussen, Edmund J.

AU - Gregory, Duncan H.

PY - 2019/3/1

Y1 - 2019/3/1

N2 - New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

AB - New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

KW - lithium alanates

KW - borohydrides

KW - LiBH4

KW - electrochemical stability

UR - https://www.scopus.com/pages/publications/85062846333

U2 - 10.1039/c9qi00099b

DO - 10.1039/c9qi00099b

M3 - Article

AN - SCOPUS:85062846333

VL - 6

SP - 808

EP - 812

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 3

ER -

Molecular-salt hybrids; integration of ammonia borane into lithium halides

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this