Molecular-salt hybrids; integration of ammonia borane into lithium halides

Irene Cascallana-Matías, Joachim Breternitz, Annabelle Baker, Hallam Davis, Edmund J. Cussen, Duncan H. Gregory

Research output: Contribution to journalArticle

Abstract

New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

LanguageEnglish
Pages808-812
Number of pages5
JournalInorganic Chemistry Frontiers
Volume6
Issue number3
Early online date18 Feb 2019
DOIs
Publication statusPublished - 1 Mar 2019

Fingerprint

Boranes
Lithium
Ammonia
Salts
Hydrogen
Ions
Decomposition

Keywords

  • lithium alanates
  • borohydrides
  • LiBH4
  • electrochemical stability

Cite this

Cascallana-Matías, I., Breternitz, J., Baker, A., Davis, H., Cussen, E. J., & Gregory, D. H. (2019). Molecular-salt hybrids; integration of ammonia borane into lithium halides. 6(3), 808-812. https://doi.org/10.1039/c9qi00099b
Cascallana-Matías, Irene ; Breternitz, Joachim ; Baker, Annabelle ; Davis, Hallam ; Cussen, Edmund J. ; Gregory, Duncan H. / Molecular-salt hybrids; integration of ammonia borane into lithium halides. 2019 ; Vol. 6, No. 3. pp. 808-812.
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Cascallana-Matías, I, Breternitz, J, Baker, A, Davis, H, Cussen, EJ & Gregory, DH 2019, 'Molecular-salt hybrids; integration of ammonia borane into lithium halides' vol. 6, no. 3, pp. 808-812. https://doi.org/10.1039/c9qi00099b

Molecular-salt hybrids; integration of ammonia borane into lithium halides. / Cascallana-Matías, Irene; Breternitz, Joachim; Baker, Annabelle; Davis, Hallam; Cussen, Edmund J.; Gregory, Duncan H.

Vol. 6, No. 3, 01.03.2019, p. 808-812.

Research output: Contribution to journalArticle

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AU - Cascallana-Matías, Irene

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AU - Baker, Annabelle

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AU - Cussen, Edmund J.

AU - Gregory, Duncan H.

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Cascallana-Matías I, Breternitz J, Baker A, Davis H, Cussen EJ, Gregory DH. Molecular-salt hybrids; integration of ammonia borane into lithium halides. 2019 Mar 1;6(3):808-812. https://doi.org/10.1039/c9qi00099b