Factors governing the intermetallic ratios and coordination geometries in lithium amidomagnesiates are discussed with reference to three model crystal structures containing the same (dibenzylamido) ligand, which remarkably reveal that an unsolvated lithium can induce coordination expansion about a magnesium centre.
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - 21 Mar 1994|
- crystal structure
- aryl compounds
- metal alkyl