Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

D.R. Armstrong; A.R. Kennedy; R.E. Mulvey; R.B. Rowlings

doi:10.1002/(SICI)1521-3773(19990115)38:1/2<131::AID-ANIE131>3.0.CO;2-9

Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

D.R. Armstrong, A.R. Kennedy, R.E. Mulvey, R.B. Rowlings

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

90 Citations (Scopus)

Abstract

A remarkable pair of macrocyclic amides has been synthesized and crystallographically characterized; these consist of a twelve-membered (N6Na4Mg2)2+ cationic ring host with [C6H3(CH3)]2- or (C6H4)2- dianionic guests (see picture) derived from toluene and benzene, respectively.

Original language	English
Pages (from-to)	131-133
Number of pages	2
Journal	Angewandte Chemie
Volume	38
Issue number	1-2
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990115)38:1/2<131::AID-ANIE131>3.0.CO;2-9
Publication status	Published - 15 Jan 1999

Keywords

macrocyclic amides
crystallographically
toluene
benzene

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10.1002/(SICI)1521-3773(19990115)38:1/2<131::AID-ANIE131>3.0.CO;2-9

Cite this

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title = "Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules",

abstract = "A remarkable pair of macrocyclic amides has been synthesized and crystallographically characterized; these consist of a twelve-membered (N6Na4Mg2)2+ cationic ring host with [C6H3(CH3)]2- or (C6H4)2- dianionic guests (see picture) derived from toluene and benzene, respectively.",

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author = "D.R. Armstrong and A.R. Kennedy and R.E. Mulvey and R.B. Rowlings",

year = "1999",

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T1 - Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

AU - Armstrong, D.R.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

AU - Rowlings, R.B.

PY - 1999/1/15

Y1 - 1999/1/15

N2 - A remarkable pair of macrocyclic amides has been synthesized and crystallographically characterized; these consist of a twelve-membered (N6Na4Mg2)2+ cationic ring host with [C6H3(CH3)]2- or (C6H4)2- dianionic guests (see picture) derived from toluene and benzene, respectively.

AB - A remarkable pair of macrocyclic amides has been synthesized and crystallographically characterized; these consist of a twelve-membered (N6Na4Mg2)2+ cationic ring host with [C6H3(CH3)]2- or (C6H4)2- dianionic guests (see picture) derived from toluene and benzene, respectively.

KW - macrocyclic amides

KW - crystallographically

KW - toluene

KW - benzene

UR - http://dx.doi.org/10.1002/(SICI)1521-3773(19990115)38:1/2<131::AID-ANIE131>3.0.CO;2-9

U2 - 10.1002/(SICI)1521-3773(19990115)38:1/2<131::AID-ANIE131>3.0.CO;2-9

DO - 10.1002/(SICI)1521-3773(19990115)38:1/2<131::AID-ANIE131>3.0.CO;2-9

M3 - Article

SN - 0044-8249

VL - 38

SP - 131

EP - 133

JO - Angewandte Chemie

JF - Angewandte Chemie

IS - 1-2

ER -

Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

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Keywords

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Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

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