Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

D.R. Armstrong, A.R. Kennedy, R.E. Mulvey, R.B. Rowlings

Research output: Contribution to journalArticle

73 Citations (Scopus)

Abstract

A remarkable pair of macrocyclic amides has been synthesized and crystallographically characterized; these consist of a twelve-membered (N6Na4Mg2)2+ cationic ring host with [C6H3(CH3)]2- or (C6H4)2- dianionic guests (see picture) derived from toluene and benzene, respectively.
LanguageEnglish
Pages131-133
Number of pages2
JournalAngewandte Chemie
Volume38
Issue number1-2
DOIs
Publication statusPublished - 15 Jan 1999

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Toluene
Benzene
Amides
Magnesium
Metals
Sodium

Keywords

  • macrocyclic amides
  • crystallographically
  • toluene
  • benzene

Cite this

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Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules. / Armstrong, D.R.; Kennedy, A.R.; Mulvey, R.E.; Rowlings, R.B.

In: Angewandte Chemie, Vol. 38, No. 1-2, 15.01.1999, p. 131-133.

Research output: Contribution to journalArticle

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KW - benzene

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