Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain

Kenneth W. Henderson; Robert Mulvey; Friedrich B. M. Reinhard; William Clegg; Lynne Horsburgh

doi:10.1021/ja00102a050

Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain

Kenneth W. Henderson, Robert Mulvey, Friedrich B. M. Reinhard, William Clegg, Lynne Horsburgh

Pure And Applied Chemistry

Research output: Contribution to journal › Comment/debate

28 Citations (Scopus)

Abstract

Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis
Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.

Original language	English
Pages (from-to)	10777-10778
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	116
Issue number	23
DOIs	https://doi.org/10.1021/ja00102a050
Publication status	Published - 16 Nov 1994

Keywords

organomagnesium compounds
metal alkyl
complex

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10.1021/ja00102a050

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Henderson, K. W., Mulvey, R., Reinhard, F. B. M., Clegg, W., & Horsburgh, L. (1994). Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. Journal of the American Chemical Society, 116(23), 10777-10778. https://doi.org/10.1021/ja00102a050

Henderson, Kenneth W. ; Mulvey, Robert ; Reinhard, Friedrich B. M. ; Clegg, William ; Horsburgh, Lynne. / Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. In: Journal of the American Chemical Society. 1994 ; Vol. 116, No. 23. pp. 10777-10778.

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title = "Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain",

abstract = "Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.",

keywords = "organomagnesium compounds, metal alkyl, complex",

author = "Henderson, {Kenneth W.} and Robert Mulvey and Reinhard, {Friedrich B. M.} and William Clegg and Lynne Horsburgh",

year = "1994",

month = nov,

day = "16",

doi = "10.1021/ja00102a050",

language = "English",

volume = "116",

pages = "10777--10778",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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Henderson, KW, Mulvey, R, Reinhard, FBM, Clegg, W & Horsburgh, L 1994, 'Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain', Journal of the American Chemical Society, vol. 116, no. 23, pp. 10777-10778. https://doi.org/10.1021/ja00102a050

Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. / Henderson, Kenneth W.; Mulvey, Robert; Reinhard, Friedrich B. M.; Clegg, William; Horsburgh, Lynne.

In: Journal of the American Chemical Society, Vol. 116, No. 23, 16.11.1994, p. 10777-10778.

Research output: Contribution to journal › Comment/debate

TY - JOUR

T1 - Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain

AU - Henderson, Kenneth W.

AU - Mulvey, Robert

AU - Reinhard, Friedrich B. M.

AU - Clegg, William

AU - Horsburgh, Lynne

PY - 1994/11/16

Y1 - 1994/11/16

N2 - Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.

AB - Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.

KW - organomagnesium compounds

KW - metal alkyl

KW - complex

U2 - 10.1021/ja00102a050

DO - 10.1021/ja00102a050

M3 - Comment/debate

VL - 116

SP - 10777

EP - 10778

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 23

ER -

Henderson KW, Mulvey R, Reinhard FBM, Clegg W, Horsburgh L. Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. Journal of the American Chemical Society. 1994 Nov 16;116(23):10777-10778. https://doi.org/10.1021/ja00102a050