Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain

Kenneth W. Henderson, Robert Mulvey, Friedrich B. M. Reinhard, William Clegg, Lynne Horsburgh

Research output: Contribution to journal › Comment/debate

28 Citations (Scopus)

Abstract

Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis
Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.
Original languageEnglish
Pages (from-to)10777-10778
Number of pages2
JournalJournal of the American Chemical Society
Volume116
Issue number23
DOIs
Publication statusPublished - 16 Nov 1994

Fingerprint

cresol
Magnesium Compounds
Lithium Compounds
Magnesium Oxide
Magnesia
Lithium
Oxides
Magnesium
Intermetallics
Crystal structure
Nuclear magnetic resonance
2-cresol

Keywords

  • organomagnesium compounds
  • metal alkyl
  • complex

Cite this

Henderson, Kenneth W. ; Mulvey, Robert ; Reinhard, Friedrich B. M. ; Clegg, William ; Horsburgh, Lynne. / Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. In: Journal of the American Chemical Society. 1994 ; Vol. 116, No. 23. pp. 10777-10778.
@article{47121828cdea4de68856c08807ff8567,
title = "Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain",
abstract = "Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.",
keywords = "organomagnesium compounds, metal alkyl, complex",
author = "Henderson, {Kenneth W.} and Robert Mulvey and Reinhard, {Friedrich B. M.} and William Clegg and Lynne Horsburgh",
year = "1994",
month = "11",
day = "16",
doi = "10.1021/ja00102a050",
language = "English",
volume = "116",
pages = "10777--10778",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "23",

}

Henderson, KW, Mulvey, R, Reinhard, FBM, Clegg, W & Horsburgh, L 1994, 'Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain', Journal of the American Chemical Society, vol. 116, no. 23, pp. 10777-10778. https://doi.org/10.1021/ja00102a050

Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. / Henderson, Kenneth W.; Mulvey, Robert; Reinhard, Friedrich B. M.; Clegg, William; Horsburgh, Lynne.

In: Journal of the American Chemical Society, Vol. 116, No. 23, 16.11.1994, p. 10777-10778.

Research output: Contribution to journal › Comment/debate

TY - JOUR

T1 - Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain

AU - Henderson, Kenneth W.

AU - Mulvey, Robert

AU - Reinhard, Friedrich B. M.

AU - Clegg, William

AU - Horsburgh, Lynne

PY - 1994/11/16

Y1 - 1994/11/16

N2 - Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.

AB - Intermetallic organoelement compounds of lithium and magnesium, lithium magnesiates, are still numerically rare, even though over 40 years has passed since their initial synthesis Reported herein is the extension of this class of compound to aryl oxides, derived from o-cresol.

KW - organomagnesium compounds

KW - metal alkyl

KW - complex

U2 - 10.1021/ja00102a050

DO - 10.1021/ja00102a050

M3 - Comment/debate

VL - 116

SP - 10777

EP - 10778

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 23

ER -

Henderson KW, Mulvey R, Reinhard FBM, Clegg W, Horsburgh L. Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. Journal of the American Chemical Society. 1994 Nov 16;116(23):10777-10778. https://doi.org/10.1021/ja00102a050

Access to Document