Abstract
| Language | English |
|---|---|
| Pages | 8375-8378 |
| Number of pages | 4 |
| Journal | Angewandte Chemie |
| Volume | 50 |
| Issue number | 36 |
| DOIs | |
| Publication status | Published - 19 Jul 2011 |
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Keywords
- amide–lithium halide compounds
- anionic crowns
- salt effect
- lithium
- halides
- inverse crowns
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Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns. / Kennedy, Alan; Mulvey, Robert; O'Hara, Charles; Robertson, Gemma; Robertson, Stuart.
In: Angewandte Chemie, Vol. 50, No. 36, 19.07.2011, p. 8375-8378.Research output: Contribution to journal › Article
TY - JOUR
T1 - Mixed lithium amide–lithium halide compounds
T2 - Angewandte Chemie International Edition
AU - Kennedy, Alan
AU - Mulvey, Robert
AU - O'Hara, Charles
AU - Robertson, Gemma
AU - Robertson, Stuart
PY - 2011/7/19
Y1 - 2011/7/19
N2 - The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).
AB - The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).
KW - amide–lithium halide compounds
KW - anionic crowns
KW - salt effect
KW - lithium
KW - halides
KW - inverse crowns
U2 - 10.1002/anie.201102023
DO - 10.1002/anie.201102023
M3 - Article
VL - 50
SP - 8375
EP - 8378
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 36
ER -