Projects per year
Abstract
The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).
Original language | English |
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Pages (from-to) | 8375-8378 |
Number of pages | 4 |
Journal | Angewandte Chemie |
Volume | 50 |
Issue number | 36 |
DOIs | |
Publication status | Published - 19 Jul 2011 |
Keywords
- amide–lithium halide compounds
- anionic crowns
- salt effect
- lithium
- halides
- inverse crowns
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Dive into the research topics of 'Mixed lithium amide–lithium halide compounds: unusual halide-deficient amido metal anionic crowns'. Together they form a unique fingerprint.Projects
- 2 Finished
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ENANTIOSELECTIVE APPLICATIONS OF DESIGNER SYNERGIC REAGENTS (First Grant)
O'Hara, C. (Principal Investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/10/08 → 31/03/12
Project: Research
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EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)
Mulvey, R. (Principal Investigator) & Kennedy, A. (Co-investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/10/08 → 31/03/12
Project: Research