Mixed lithium amide–lithium halide compounds: unusual halide-deficient amido metal anionic crowns

Alan Kennedy; Robert Mulvey; Charles O'Hara; Gemma Robertson; Stuart Robertson

doi:10.1002/anie.201102023

Mixed lithium amide–lithium halide compounds: unusual halide-deficient amido metal anionic crowns

Alan Kennedy, Robert Mulvey, Charles O'Hara, Gemma Robertson, Stuart Robertson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).

Original language	English
Pages (from-to)	8375-8378
Number of pages	4
Journal	Angewandte Chemie
Volume	50
Issue number	36
DOIs	https://doi.org/10.1002/anie.201102023
Publication status	Published - 19 Jul 2011

Keywords

amide–lithium halide compounds
anionic crowns
salt effect
lithium
halides
inverse crowns

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10.1002/anie.201102023

2 Finished

ENANTIOSELECTIVE APPLICATIONS OF DESIGNER SYNERGIC REAGENTS (First Grant)
O'Hara, C.
EPSRC (Engineering and Physical Sciences Research Council)
1/10/08 → 31/03/12
Project: Research
EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)
Mulvey, R. & Kennedy, A.
EPSRC (Engineering and Physical Sciences Research Council)
1/10/08 → 31/03/12
Project: Research

Cite this

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title = "Mixed lithium amide–lithium halide compounds: unusual halide-deficient amido metal anionic crowns",

abstract = "The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).",

keywords = "amide–lithium halide compounds , anionic crowns, salt effect, lithium, halides, inverse crowns",

author = "Alan Kennedy and Robert Mulvey and Charles O'Hara and Gemma Robertson and Stuart Robertson",

year = "2011",

month = jul,

day = "19",

doi = "10.1002/anie.201102023",

language = "English",

volume = "50",

pages = "8375--8378",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

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TY - JOUR

T1 - Mixed lithium amide–lithium halide compounds

T2 - unusual halide-deficient amido metal anionic crowns

AU - Kennedy, Alan

AU - Mulvey, Robert

AU - O'Hara, Charles

AU - Robertson, Gemma

AU - Robertson, Stuart

PY - 2011/7/19

Y1 - 2011/7/19

N2 - The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).

AB - The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).

KW - amide–lithium halide compounds

KW - anionic crowns

KW - salt effect

KW - lithium

KW - halides

KW - inverse crowns

U2 - 10.1002/anie.201102023

DO - 10.1002/anie.201102023

M3 - Article

VL - 50

SP - 8375

EP - 8378

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 36

ER -

Mixed lithium amide–lithium halide compounds: unusual halide-deficient amido metal anionic crowns

Abstract

Keywords

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Projects

ENANTIOSELECTIVE APPLICATIONS OF DESIGNER SYNERGIC REAGENTS (First Grant)

EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)

Cite this