Mixed lithium amide–lithium halide compounds: unusual halide-deficient amido metal anionic crowns

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24 Citations (Scopus)

Abstract

The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).
Original languageEnglish
Pages (from-to)8375-8378
Number of pages4
JournalAngewandte Chemie
Volume50
Issue number36
DOIs
Publication statusPublished - 19 Jul 2011

Keywords

  • amide–lithium halide compounds
  • anionic crowns
  • salt effect
  • lithium
  • halides
  • inverse crowns

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