Metal-organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

Charlotte L. Smith; Rob Clowes; Reiner Sebastian Sprick; Andrew I. Cooper; Alexander J. Cowan

doi:10.1039/c9se00450e

Metal-organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

Charlotte L. Smith, Rob Clowes, Reiner Sebastian Sprick, Andrew I. Cooper, Alexander J. Cowan

Pure And Applied Chemistry

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15 Citations (Scopus)

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Abstract

A metal-organic conjugated micorporous polymer (CMP) containing a manganese carbonyl electrocatalyst for CO₂ reduction has been synthesised and electrochemically characterised. Incorporation in a rigid framework changes the behavior of the catalyst, preventing reductive dimerization. These initial studies demonstrate the feasibility of CMP electrodes that can provide both high local CO₂ concentrations and well defined electrocatalytic sites.

Original language	English
Pages (from-to)	2990-2994
Number of pages	5
Journal	Sustainable Energy and Fuels
Volume	3
Issue number	11
Early online date	9 Sept 2019
DOIs	https://doi.org/10.1039/c9se00450e
Publication status	Published - 1 Nov 2019

Keywords

conjugated micorporous polymer
manganese carbonyl electrocatalyst
carbon reduction

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10.1039/c9se00450e

Smith-etal-SEF-2019-Metal-organic-conjugated-microporous-polymer-containing-a-carbonAccepted author manuscript, 1.4 MB

https://livrepository.liverpool.ac.uk/3053977/

Cite this

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AU - Smith, Charlotte L.

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AU - Sprick, Reiner Sebastian

AU - Cooper, Andrew I.

AU - Cowan, Alexander J.

PY - 2019/11/1

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AB - A metal-organic conjugated micorporous polymer (CMP) containing a manganese carbonyl electrocatalyst for CO2 reduction has been synthesised and electrochemically characterised. Incorporation in a rigid framework changes the behavior of the catalyst, preventing reductive dimerization. These initial studies demonstrate the feasibility of CMP electrodes that can provide both high local CO2 concentrations and well defined electrocatalytic sites.

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KW - manganese carbonyl electrocatalyst

KW - carbon reduction

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JF - Sustainable Energy and Fuels

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ER -

Metal-organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

Abstract

Keywords

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