Metal-organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

Charlotte L. Smith, Rob Clowes, Reiner Sebastian Sprick, Andrew I. Cooper, Alexander J. Cowan

Research output: Contribution to journalArticle

2 Citations (Scopus)
33 Downloads (Pure)

Abstract

A metal-organic conjugated micorporous polymer (CMP) containing a manganese carbonyl electrocatalyst for CO2 reduction has been synthesised and electrochemically characterised. Incorporation in a rigid framework changes the behavior of the catalyst, preventing reductive dimerization. These initial studies demonstrate the feasibility of CMP electrodes that can provide both high local CO2 concentrations and well defined electrocatalytic sites.

Original languageEnglish
Pages (from-to)2990-2994
Number of pages5
JournalSustainable Energy and Fuels
Volume3
Issue number11
Early online date9 Sep 2019
DOIs
Publication statusPublished - 1 Nov 2019

Keywords

  • conjugated micorporous polymer
  • manganese carbonyl electrocatalyst
  • carbon reduction

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