A convenient one-pot palladium-catalyzed cascade process for the prepn. of both benzoxazoles and benzothiazoles has been developed. While these reactions proceed to give similar compds. the mechanisms governing the processes are different as are the exptl. conditions employed.
- mechanistic exploration
- palladium-catalysed process
- t one-pot palladium-catalyzed cascade process
Bochatay, V., Boissarie, P., Murphy, J. A., Suckling, C., & Lang, S. (2013). Mechanistic exploration of the palladium-catalysed process for the synthesis of benzoxazoles and benzothiazoles. Journal of Organic Chemistry, 78(4), 1471-1477. https://doi.org/10.1021/jo302544d