Luminescence of the Cr3+ ions doped in PLZT ceramics

T. P. J. Han; M. T. Jardiel; M. Villegas; A. C. Caballero; D. Bravo; F. Jaque

doi:10.1016/j.cplett.2011.03.034

Luminescence of the Cr3+ ions doped in PLZT ceramics

T. P. J. Han, M. T. Jardiel, M. Villegas, A. C. Caballero, D. Bravo, F. Jaque

Research output: Contribution to journal › Article › peer-review

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Abstract

The photoluminescence properties of Cr-doped PLZT-9/65/35 (Pb0.95La0.09Zr0.65Ti0.35O3) have been studied. The fluorescence spectra consist of two inhomogeneously broadened narrow bands centred at similar to 734 and 740 nm and a broadband emission with a maximum at similar to 1000 nm. The two high energy bands have been assigned to the E-2(T-2(1)) -> (4)A(2) transition of two Cr3+ defect centres in octahedral site with high/ intermediate crystal field strength whereas the near infrared emission is tentatively assigned to the overlapping of the broadband emission of the Cr3+ ions defect centre's T-4(2) -> (4)A(2) transition and the emission of the Cr5+ ions' E-2 -> T-2(2) transition. (c) 2011 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	201-204
Number of pages	4
Journal	Chemical Physics Letters
Volume	506
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2011.03.034
Publication status	Published - 20 Apr 2011

Keywords

photoluminescence
broadband emission
infrared emission
crystal field strength

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10.1016/j.cplett.2011.03.034

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title = "Luminescence of the Cr3+ ions doped in PLZT ceramics",

abstract = "The photoluminescence properties of Cr-doped PLZT-9/65/35 (Pb0.95La0.09Zr0.65Ti0.35O3) have been studied. The fluorescence spectra consist of two inhomogeneously broadened narrow bands centred at similar to 734 and 740 nm and a broadband emission with a maximum at similar to 1000 nm. The two high energy bands have been assigned to the E-2(T-2(1)) -> (4)A(2) transition of two Cr3+ defect centres in octahedral site with high/ intermediate crystal field strength whereas the near infrared emission is tentatively assigned to the overlapping of the broadband emission of the Cr3+ ions defect centre's T-4(2) -> (4)A(2) transition and the emission of the Cr5+ ions' E-2 -> T-2(2) transition. (c) 2011 Elsevier B.V. All rights reserved.",

keywords = "photoluminescence, broadband emission , infrared emission , crystal field strength",

author = "Han, \{T. P. J.\} and Jardiel, \{M. T.\} and M. Villegas and Caballero, \{A. C.\} and D. Bravo and F. Jaque",

year = "2011",

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doi = "10.1016/j.cplett.2011.03.034",

language = "English",

volume = "506",

pages = "201--204",

journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Luminescence of the Cr3+ ions doped in PLZT ceramics

AU - Han, T. P. J.

AU - Jardiel, M. T.

AU - Villegas, M.

AU - Caballero, A. C.

AU - Bravo, D.

AU - Jaque, F.

PY - 2011/4/20

Y1 - 2011/4/20

N2 - The photoluminescence properties of Cr-doped PLZT-9/65/35 (Pb0.95La0.09Zr0.65Ti0.35O3) have been studied. The fluorescence spectra consist of two inhomogeneously broadened narrow bands centred at similar to 734 and 740 nm and a broadband emission with a maximum at similar to 1000 nm. The two high energy bands have been assigned to the E-2(T-2(1)) -> (4)A(2) transition of two Cr3+ defect centres in octahedral site with high/ intermediate crystal field strength whereas the near infrared emission is tentatively assigned to the overlapping of the broadband emission of the Cr3+ ions defect centre's T-4(2) -> (4)A(2) transition and the emission of the Cr5+ ions' E-2 -> T-2(2) transition. (c) 2011 Elsevier B.V. All rights reserved.

AB - The photoluminescence properties of Cr-doped PLZT-9/65/35 (Pb0.95La0.09Zr0.65Ti0.35O3) have been studied. The fluorescence spectra consist of two inhomogeneously broadened narrow bands centred at similar to 734 and 740 nm and a broadband emission with a maximum at similar to 1000 nm. The two high energy bands have been assigned to the E-2(T-2(1)) -> (4)A(2) transition of two Cr3+ defect centres in octahedral site with high/ intermediate crystal field strength whereas the near infrared emission is tentatively assigned to the overlapping of the broadband emission of the Cr3+ ions defect centre's T-4(2) -> (4)A(2) transition and the emission of the Cr5+ ions' E-2 -> T-2(2) transition. (c) 2011 Elsevier B.V. All rights reserved.

KW - photoluminescence

KW - broadband emission

KW - infrared emission

KW - crystal field strength

UR - https://www.scopus.com/pages/publications/79954569178

U2 - 10.1016/j.cplett.2011.03.034

DO - 10.1016/j.cplett.2011.03.034

M3 - Article

SN - 0009-2614

VL - 506

SP - 201

EP - 204

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Luminescence of the Cr3+ ions doped in PLZT ceramics

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Keywords

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